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Magnetic order in a metal thiocyanate perovskite-analogue (2022)
Journal Article
Cliffe, M. J., Fabelo, O., & CaƱadillas-Delgado, L. (2022). Magnetic order in a metal thiocyanate perovskite-analogue. CrystEngComm, https://doi.org/10.1039/d2ce00649a

Metal thiocyanate perovskite-analogues are a growing class of materials, but although they contain paramagnetic cations there have been no reports of their magnetic properties. Due to the large separations between the paramagnetic cations, with a sho... Read More about Magnetic order in a metal thiocyanate perovskite-analogue.

The Structures of Ordered Defects in Thiocyanate Analogues of Prussian Blue (2020)
Journal Article
Cliffe, M., Keyzer, E., Bond, A., Astle, M. A., & Grey, C. (2020). The Structures of Ordered Defects in Thiocyanate Analogues of Prussian Blue. Chemical Science, 11(17), 4430-4438. https://doi.org/10.1039/D0SC01246G

We report the structures of six new divalent transition metal hexathiocyanatobismuthate frame- works with the generic formula {M[Bi(SCN)6]2+x }x− {guest}x+, M = Mn, Co, Ni and Zn. These 3 frameworks are defective analogues of the perovskite-derived... Read More about The Structures of Ordered Defects in Thiocyanate Analogues of Prussian Blue.