Stabilization of Polyoxometalate Charge Carriers via Redox‐Driven Nanoconfinement in Single‐Walled Carbon Nanotubes

Jordan, Jack W.; Cameron, Jamie M.; Lowe, Grace A.; Rance, Graham A.; Fung, Kayleigh L. Y.; Johnson, Lee R.; Walsh, Darren A.; Khlobystov, Andrei N.; Newton, Graham N.

doi:10.1002/ange.202115619

All Outputs (7)

Host–Guest Chemistry in Boron Nitride Nanotubes: Interactions with Polyoxometalates and Mechanism of Encapsulation (2022)
Journal Article

Boron nitride nanotubes (BNNTs) are an emerging class of molecular container offering new functionalities and possibilities for studying molecules at the nanoscale. Herein, BNNTs are demonstrated as highly effective nanocontainers for polyoxometalate... Read More about Host–Guest Chemistry in Boron Nitride Nanotubes: Interactions with Polyoxometalates and Mechanism of Encapsulation.

Enflurane Additive for Sodium Negative Electrodes (2022)
Journal Article

Development of sodium anodes, both hard carbon (HC) and metallic, is dependent on the discovery of electrolyte formations and additives able to stabilize the interphase and support Na+ transport. Halogen salt additives are known to lower the energy b... Read More about Enflurane Additive for Sodium Negative Electrodes.

Synthesis of New Morphinan Opioids by TBADT‐Catalyzed Photochemical Functionalization at the Carbon Skeleton (2022)
Journal Article

The synthesis of new morphinan opioids by the addition of photochemically generated carbon-centered radicals to substrates containing an enone in the morphinan C-ring, is described. Using tetrabutylammonium decatungstate (TBADT) as a hydrogen atom tr... Read More about Synthesis of New Morphinan Opioids by TBADT‐Catalyzed Photochemical Functionalization at the Carbon Skeleton.

A Mixed‐Addenda Mo/W Organofunctionalised Hybrid Polyoxometalate (2022)
Journal Article

Substitution of metal addenda was explored as a method to modulate the electronic structure of organofunctionalised hybrid polyoxometalate clusters. Here we study the effects of Mo substitution into a W-based cluster. Through a range of spectroscopic... Read More about A Mixed‐Addenda Mo/W Organofunctionalised Hybrid Polyoxometalate.

Redox-active hierarchical assemblies of hybrid polyoxometalate nanostructures at carbon surfaces (2022)
Journal Article

The self-assembly of hierarchical nanostructures on surfaces is a promising strategy for the development of a wide range of new technologies, such as energy-storage devices and sensors. In this work we show that amphiphilic, organofunctionalized hybr... Read More about Redox-active hierarchical assemblies of hybrid polyoxometalate nanostructures at carbon surfaces.

Stabilization of Polyoxometalate Charge Carriers via Redox‐Driven Nanoconfinement in Single‐Walled Carbon Nanotubes (2022)
Journal Article

We describe the preparation of hybrid redox materials based on polyoxomolybdates encapsulated within single-walled carbon nanotubes (SWNTs). Polyoxomolybdates readily oxidize SWNTs under ambient conditions in solution, and here we study their charge-... Read More about Stabilization of Polyoxometalate Charge Carriers via Redox‐Driven Nanoconfinement in Single‐Walled Carbon Nanotubes.