A Mixed‐Addenda Mo/W Organofunctionalised Hybrid Polyoxometalate

Amin, Sharad S.; Cameron, Jamie M.; Winslow, Max; Davies, E. Stephen; Argent, Stephen P.; Robinson, David; Newton, Graham N.

Abstract

Substitution of metal addenda was explored as a method to modulate the electronic structure of organofunctionalised hybrid polyoxometalate clusters. Here we study the effects of Mo substitution into a W-based cluster. Through a range of spectroscopic and electrochemical techniques, substitution of W for Mo was shown to significantly modify the frontier orbital energies of the hybrid cluster.

Citation

Amin, S. S., Cameron, J. M., Winslow, M., Davies, E. S., Argent, S. P., Robinson, D., & Newton, G. N. (2022). A Mixed‐Addenda Mo/W Organofunctionalised Hybrid Polyoxometalate. European Journal of Inorganic Chemistry, 2022(10), Article e202200019. https://doi.org/10.1002/ejic.202200019

• Journal Article Type: Article
• Acceptance Date: Feb 24, 2022
• Online Publication Date: Mar 10, 2022
• Publication Date: Apr 8, 2022
• Deposit Date: Mar 11, 2022
• Publicly Available Date: Mar 11, 2022
• Journal: European Journal of Inorganic Chemistry
• Print ISSN: 1434-1948
• Electronic ISSN: 1099-0682
• Publisher: Wiley
• Peer Reviewed: Peer Reviewed
• Volume: 2022
• Issue: 10
• Article Number: e202200019
• DOI: https://doi.org/10.1002/ejic.202200019
• Keywords: Inorganic Chemistry
• Public URL: https://nottingham-repository.worktribe.com/output/7571037
• Publisher URL: https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202200019