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A Mixed‐Addenda Mo/W Organofunctionalised Hybrid Polyoxometalate

Amin, Sharad S.; Cameron, Jamie M.; Winslow, Max; Davies, E. Stephen; Argent, Stephen P.; Robinson, David; Newton, Graham N.

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Authors

Sharad S. Amin

Jamie M. Cameron

Max Winslow

David Robinson



Abstract

Substitution of metal addenda was explored as a method to modulate the electronic structure of organofunctionalised hybrid polyoxometalate clusters. Here we study the effects of Mo substitution into a W-based cluster. Through a range of spectroscopic and electrochemical techniques, substitution of W for Mo was shown to significantly modify the frontier orbital energies of the hybrid cluster.

Citation

Amin, S. S., Cameron, J. M., Winslow, M., Davies, E. S., Argent, S. P., Robinson, D., & Newton, G. N. (2022). A Mixed‐Addenda Mo/W Organofunctionalised Hybrid Polyoxometalate. European Journal of Inorganic Chemistry, 2022(10), Article e202200019. https://doi.org/10.1002/ejic.202200019

Journal Article Type Article
Acceptance Date Feb 24, 2022
Online Publication Date Mar 10, 2022
Publication Date Apr 8, 2022
Deposit Date Mar 11, 2022
Publicly Available Date Mar 11, 2022
Journal European Journal of Inorganic Chemistry
Print ISSN 1434-1948
Electronic ISSN 1099-0682
Publisher Wiley
Peer Reviewed Peer Reviewed
Volume 2022
Issue 10
Article Number e202200019
DOI https://doi.org/10.1002/ejic.202200019
Keywords Inorganic Chemistry
Public URL https://nottingham-repository.worktribe.com/output/7571037
Publisher URL https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.202200019

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