Selective electrochemical CO 2 conversion with a hybrid polyoxometalate

Kuramochi, Satoshi; Cameron, Jamie M.; Fukui, Tomoya; Jones, Kieran D.; Argent, Stephen P.; Kusaka, Shinpei; Shiraishi, Ryo; Tamaki, Yusuke; Yatsu, Taiki; Shiga, Takuya; Ishitani, Osamu; Oshio, Hiroki; Newton, Graham N.

Abstract

A multi-component coordination compound, in which ruthenium antenna complexes are connected to a polyoxotungstate core is presented. This hybrid cluster effectively promotes the electrochemical conversion of CO2 to C1 feedstocks, the selectivity of which can be controlled by the acidity of the media.

Citation

Kuramochi, S., Cameron, J. M., Fukui, T., Jones, K. D., Argent, S. P., Kusaka, S., …Newton, G. N. (2023). Selective electrochemical CO 2 conversion with a hybrid polyoxometalate. Chemical Communications, 59(72), 10801-10804. https://doi.org/10.1039/d3cc02138f

• Journal Article Type: Article
• Acceptance Date: Aug 1, 2023
• Online Publication Date: Aug 9, 2023
• Publication Date: Sep 16, 2023
• Deposit Date: Aug 30, 2023
• Publicly Available Date: Sep 1, 2023
• Journal: Chemical Communications
• Print ISSN: 1359-7345
• Electronic ISSN: 1364-548X
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 59
• Issue: 72
• Pages: 10801-10804
• DOI: https://doi.org/10.1039/d3cc02138f
• Keywords: Materials Chemistry; Metals and Alloys; Surfaces, Coatings and Films; General Chemistry; Ceramics and Composites; Electronic, Optical and Magnetic Materials; Catalysis
• Public URL: https://nottingham-repository.worktribe.com/output/24569889
• Publisher URL: https://pubs.rsc.org/en/content/articlelanding/2023/CC/D3CC02138F