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Probing the electronic environment of binary and ternary ionic liquid mixtures by x-ray photoelectron spectroscopy

Men, Shuang; Licence, Peter

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Authors

Shuang Men



Abstract

X-ray photoelectron spectroscopy is used to probe the electronic environment of cations and anions for three binary and one ternary chlorostannate ionic liquid mixtures. The impact of the weighting of Cl on the electronic environment of the cation-based nitrogen atom is revealed in detail. With the increasing of the concentration of Cl , the N 1s binding energy is decreased. The electronic environment of the anion- based component is also compared based upon Sn 3d5/2 and Cl 2p3/2 binding energies. It is found that with the increasing of the weighting of Cl , binding energies of Sn 3d5/2 and Cl 2p3/2 both decrease.

Citation

Men, S., & Licence, P. (2017). Probing the electronic environment of binary and ternary ionic liquid mixtures by x-ray photoelectron spectroscopy. Chemical Physics Letters, 686, https://doi.org/10.1016/j.cplett.2017.08.034

Journal Article Type Article
Acceptance Date Aug 18, 2017
Online Publication Date Aug 19, 2017
Publication Date Oct 16, 2017
Deposit Date Sep 7, 2017
Publicly Available Date Aug 20, 2018
Journal Chemical Physics Letters
Print ISSN 0009-2614
Electronic ISSN 0009-2614
Publisher Elsevier
Peer Reviewed Peer Reviewed
Volume 686
DOI https://doi.org/10.1016/j.cplett.2017.08.034
Public URL https://nottingham-repository.worktribe.com/output/888135
Publisher URL http://www.sciencedirect.com/science/article/pii/S0009261417307959?via%3Dihub

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