ChemInform Abstract: Catalytic Hydrotrifluoromethylation of Unactivated Alkenes
(2013)
Journal Article
All Outputs (4)
Catalytic Decarboxylative Fluorination for the Synthesis of Tri- and Difluoromethyl Arenes (2013)
Journal Article
Treatment of readily available α,α-difluoro- and α-fluoroarylacetic acids with Selectfluor under Ag(I) catalysis led to decarboxylative fluorination. This operationally simple reaction gave access to tri- and difluoromethylarenes applying a late-stag... Read More about Catalytic Decarboxylative Fluorination for the Synthesis of Tri- and Difluoromethyl Arenes.
Trifluoromethylation of Allylsilanes under Photoredox Catalysis (2013)
Journal Article
A new catalytic method to access allylic secondary CF3 products is described. These reactions use the visible light excited Ru(bpy)3Cl2·6H2O catalyst and the Togni or Umemoto reagent as the CF3 source. The photoredox catalytic manifold delivers enant... Read More about Trifluoromethylation of Allylsilanes under Photoredox Catalysis.
Catalytic Hydrotrifluoromethylation of Unactivated Alkenes (2013)
Journal Article
A visible-light-mediated hydrotrifluoromethylation of unactivated alkenes that uses the Umemoto reagent as the CF3 source and MeOH as the reductant is disclosed. This effective transformation operates at room temperature in the presence of 5 mol % Ru... Read More about Catalytic Hydrotrifluoromethylation of Unactivated Alkenes.