All Outputs (8)

Carboxylic acid functionalized spin-crossover iron(II) grids for tunable switching and hybrid electrode fabrication (2018)
Journal Article

Two carboxyl-substituted iron(II) grids, one protonated, [Fe4(HL)4](BF4)4·4MeCN·AcOEt (1), and the other deprotonated, [Fe4(L)4]·DMSO·EtOH (2), where H2L = 4-{4,5-bis[6-(3,5-dimethylpyrazol-1-yl)pyrid-2-yl]-1H-imidazol-2-yl}benzoic acid, were synthes... Read More about Carboxylic acid functionalized spin-crossover iron(II) grids for tunable switching and hybrid electrode fabrication.

Physical and electrochemical modulation of polyoxometalate ionic liquids via organic functionalization (2018)
Journal Article

Tuning the electronic structure of organic–inorganic hybrid polyoxometalates: The crucial role of the covalent linkage (2018)
Journal Article

The covalent organofunctionalization of polyoxometalates (POMs) has been widely used to both control and enhance their redox properties, particularly for applications in catalysis, energy storage, optics and molecular magnetism. The design of such sy... Read More about Tuning the electronic structure of organic–inorganic hybrid polyoxometalates: The crucial role of the covalent linkage.

Cobalt complexes with redox-active anthraquinone-type ligands (2018)
Journal Article

Three anthraquinone-type multidentate ligands, HL1-3 (HL = 2-R-1H-anthra[1,2-d]imidazole6,11-dione, HL1; R = (2-pyridyl), HL2; R = (4,6-dimethyl-2-pyridyl), HL3; R = (6-methoxy-2pyridyl)), were prepared, and their complexation behaviour were investig... Read More about Cobalt complexes with redox-active anthraquinone-type ligands.

Post-functionalization of a photoactive hybrid polyoxotungstate (2018)
Journal Article

A new post-functionalization strategy for hybrid polyoxometalate (POM) clusters is presented, whereby the electronic properties and visible-light driven oxidative reactivity of the POM core can be altered by controlled addition of transition metal io... Read More about Post-functionalization of a photoactive hybrid polyoxotungstate.

3D printable photochromic molecular materials for reversible information storage (2018)
Journal Article

The formulation of advanced molecular materials with bespoke polymeric ionic liquid matrices that stabilize and solubilize hybrid organic-inorganic polyoxometalates and allow their processing by additive manufacturing, is effectively demonstrated. Th... Read More about 3D printable photochromic molecular materials for reversible information storage.

Pre-programmed self-assembly of polynuclear clusters (2018)
Journal Article

This perspective reviews our recent efforts towards the self-assembly of polynuclear clusters with ditopic and tritopic multidentate ligands HL1 (2-phenyl-4,5-bis{6-(3,5-dimethylpyrazol-1-yl)pyrid-2-yl}-1H-imidazole) and H2L2 (2,6-bis-[5-(2-pyridinyl... Read More about Pre-programmed self-assembly of polynuclear clusters.

Shining a light on the photo-sensitisation of organic-inorganic hybrid polyoxometalates (2018)
Journal Article

Finding new ways of using visible light (or, more specifically, solar irradiation) to drive commercially significant and/or challenging chemical processes is an ongoing research goal. Polyoxometalates (POMs) are discrete, metal-oxide clusters which a... Read More about Shining a light on the photo-sensitisation of organic-inorganic hybrid polyoxometalates.