Post-functionalization of a photoactive hybrid polyoxotungstate

Cameron, Jamie M.; Fujimoto, Satomi; Wei, Rong-Jia; Newton, Graham N.; Oshio, Hiroki

Abstract

A new post-functionalization strategy for hybrid polyoxometalate (POM) clusters is presented, whereby the electronic properties and visible-light driven oxidative reactivity of the POM core can be altered by controlled addition of transition metal ions. The structure of three new metal-functionalised derivatives of a phosphonate hybrid-POM are discussed, alongside a comparison of their electrochemical, photo-chemical and photo-oxidative properties.

Citation

Cameron, J. M., Fujimoto, S., Wei, R.-J., Newton, G. N., & Oshio, H. (in press). Post-functionalization of a photoactive hybrid polyoxotungstate. Dalton Transactions, https://doi.org/10.1039/C8DT01253A

• Journal Article Type: Article
• Acceptance Date: May 9, 2018
• Online Publication Date: May 15, 2018
• Deposit Date: Jun 8, 2018
• Publicly Available Date: May 16, 2019
• Journal: Dalton Transactions
• Print ISSN: 1477-9226
• Electronic ISSN: 1477-9234
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• DOI: https://doi.org/10.1039/C8DT01253A
• Public URL: https://nottingham-repository.worktribe.com/output/932685
• Publisher URL: http://pubs.rsc.org/en/content/articlelanding/2018/dt/c8dt01253a#!divAbstract
• Contract Date: Jun 8, 2018