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Optimised use of dielectric spectroscopy at microwave frequencies for direct online monitoring of polymerisation reactions (2019)
Journal Article

This study reports the first use of dielectric spectroscopy over at a wide frequency range to monitor, in real time, the progress of a ring opening polymerisation. An open-ended coaxial line sensor was placed directly into the reaction medium of a po... Read More about Optimised use of dielectric spectroscopy at microwave frequencies for direct online monitoring of polymerisation reactions.

Selective molecular annealing: in situ small angle X-ray scattering study of microwave-assisted annealing of block copolymers (2017)
Journal Article

Microwave annealing has emerged as an alternative to traditional thermal annealing approaches for optimising block copolymer self-assembly. A novel sample environment enabling small angle X-ray scattering to be performed in situ during microwave anne... Read More about Selective molecular annealing: in situ small angle X-ray scattering study of microwave-assisted annealing of block copolymers.

Exemplification of catalyst design for microwave selective heating and its application to efficient in situ catalyst synthesis (2017)
Journal Article

The use of dielectric spectroscopy to develop an underpinning understanding of the molecular transformations involved in achieving the successful, rapid in situ synthesis of a catalytic chain transfer polymerisation (CCTP) catalyst using microwave he... Read More about Exemplification of catalyst design for microwave selective heating and its application to efficient in situ catalyst synthesis.

Traceable measurement and imaging of the complex permittivity of a multiphase mineral specimen at micron scales using a microwave microscope (2016)
Journal Article

This paper describes traceable measurements of the dielectric permittivity and loss tangent of a multiphase material (particulate rock set in epoxy) at micron scales using a resonant Near-Field Scanning Microwave Microscope (NSMM) at 1.2 GHz. Calibra... Read More about Traceable measurement and imaging of the complex permittivity of a multiphase mineral specimen at micron scales using a microwave microscope.

Facile Determination of Molecular Structure Trends in Amphiphilic Core Corona Star Polymer Synthesis via Dielectric Property Measurement (2016)
Journal Article

The use of dielectric property measurements to define specific trends in the molecular structures of poly(caprolactone) containing star polymers and/or the interbatch repeatability of the synthetic procedures used to generate them is demonstrated. Th... Read More about Facile Determination of Molecular Structure Trends in Amphiphilic Core Corona Star Polymer Synthesis via Dielectric Property Measurement.

Molecular differentiated initiator reactivity in the synthesis of poly(caprolactone)-based hydrophobic homopolymer and amphiphilic core corona star polymers (2015)
Journal Article

Macromolecules that possess three-dimensional, branched molecular structures are of great interest because they exhibit significantly differentiated application performance compared to conventional linear (straight chain) polymers. This paper reports... Read More about Molecular differentiated initiator reactivity in the synthesis of poly(caprolactone)-based hydrophobic homopolymer and amphiphilic core corona star polymers.

Improving the design of industrial microwave processing systems through prediction of the dielectric properties of complex multi-layered materials (2015)
Journal Article

Rigorous design of industrial microwave processing systems requires in-depth knowledge of the dielectric properties of the materials to be processed. These values are not easy to measure, particularly when a material is multi-layered containing multi... Read More about Improving the design of industrial microwave processing systems through prediction of the dielectric properties of complex multi-layered materials.

A concise review on microwave-assisted polycondensation reactions and curing of polycondensation polymers with focus on the effect of process conditions (2014)
Journal Article

During the past 15 years, increasing application of microwave heating to polycondensation reactions has been witnessed. Experiments have been carried out at laboratory scale using widely different experimental procedures. The use of microwaves has of... Read More about A concise review on microwave-assisted polycondensation reactions and curing of polycondensation polymers with focus on the effect of process conditions.

Enhanced ‘in situ’ catalysis via microwave selective heating: catalytic chain transfer polymerisation (2014)
Journal Article

An extremely facile, single stage, ‘in-situ’, Catalytic Chain Transfer Polymerisation (CCTP) process has been identified, where the optimal polymerisation process was shown to depend upon a combination of catalyst characteristics (i.e. solubility, se... Read More about Enhanced ‘in situ’ catalysis via microwave selective heating: catalytic chain transfer polymerisation.