Iron(II)-catalyzed hydroamination of isocyanates
(2019)
Journal Article
South, A. J., Geer, A. M., Taylor, L. J., Sharpe, H. R., Lewis, W., Blake, A. J., & Kays, D. L. (2019). Iron(II)-catalyzed hydroamination of isocyanates. Organometallics, 38(21), 4115-4120. https://doi.org/10.1021/acs.organomet.9b00393
A two-coordinate Fe(II) m-terphenyl complex acts as a precatalyst for the hydroamination of isocyanates, affording urea and biuret derivatives, with product selectivity accomplished via modification of the reaction conditions. Using a more nucleophil... Read More about Iron(II)-catalyzed hydroamination of isocyanates.