Organisation and ordering of 1D porphyrin polymers synthesised by on-surface Glaser coupling

Saywell, Alexander; Browning, Abigail S.; Rahe, Philipp; Anderson, Harry L.; Beton, Peter H.

Abstract

One-dimensional polymer chains consisting of π-conjugated porphyrin units are formed via Glaser coupling on a Ag(111) surface. Scanning probe microscopy reveals the covalent structure of the products and their ordering. The conformational flexibility within the chains is investigated via a comparision of room temperature and cryogenic measurements.

Citation

Saywell, A., Browning, A. S., Rahe, P., Anderson, H. L., & Beton, P. H. (2016). Organisation and ordering of 1D porphyrin polymers synthesised by on-surface Glaser coupling. Chemical Communications, 52(68), 10342-10345. https://doi.org/10.1039/C6CC03758E

• Journal Article Type: Article
• Acceptance Date: Jun 19, 2016
• Online Publication Date: Jun 20, 2016
• Publication Date: Jun 20, 2016
• Deposit Date: Jun 23, 2016
• Publicly Available Date: Jun 23, 2016
• Journal: Chemical Communications
• Print ISSN: 1359-7345
• Electronic ISSN: 1364-548X
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 52
• Issue: 68
• Pages: 10342-10345
• DOI: https://doi.org/10.1039/C6CC03758E
• Public URL: https://nottingham-repository.worktribe.com/output/794236
• Publisher URL: http://pubs.rsc.org/en/Content/ArticleLanding/2016/CC/C6CC03758E#!divAbstract
• Contract Date: Jun 23, 2016