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Electroluminescence from a phthalocyanine monolayer encapsulated in a van der Waals tunnel diode

James, Tyler; Bradford, Jonathan; Kerfoot, James; Korolkov, Vladimir V.; Alkhamisi, Manal; Taniguchi, Takashi; Watanabe, Kenji; Nizovtsev, Anton S.; Antolín, Elisa; Besley, Elena; Svatek, Simon A.; Beton, Peter H.

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Authors

Tyler James

James Kerfoot

Vladimir V. Korolkov

Manal Alkhamisi

Takashi Taniguchi

Kenji Watanabe

Anton S. Nizovtsev

Elisa Antolín

Simon A. Svatek

PETER BETON peter.beton@nottingham.ac.uk
Professor of Physics



Abstract

Monolayers of free base phthalocyanine (H2Pc) are grown on monolayer and few-layer exfoliated flakes of hexagonal boron nitride (hBN) which are subsequently integrated into a van der Waals tunnel diode. This heterostructure consists of two thin hBN flakes between which the H2Pc monolayer is sandwiched and also incorporates upper and lower few-layer graphene contacts. When a voltage is applied between the contacts, a tunnel current flows and the embedded molecules can be excited resulting in the emission of photons with wavelengths which are close to the peaks observed in photoluminescence. We also observe electroluminescence at voltages where the energy gained by a tunnelling electron is lower than the energy of the emitted photon implying a multi-electron excitation pathway which we attribute to the formation of an intermediate triplet state. Our results provide insights into the differences in excitation and relaxation of molecules in supramolecular monolayers and bulk crystals and we discuss how the alignment of the energy levels of the molecules and contact layers determine the emission process.

Citation

James, T., Bradford, J., Kerfoot, J., Korolkov, V. V., Alkhamisi, M., Taniguchi, T., …Beton, P. H. (2023). Electroluminescence from a phthalocyanine monolayer encapsulated in a van der Waals tunnel diode. Molecular Physics, 121(7-8), Article e2197081. https://doi.org/10.1080/00268976.2023.2197081

Journal Article Type Article
Acceptance Date Mar 24, 2023
Online Publication Date Apr 13, 2023
Publication Date Apr 13, 2023
Deposit Date May 19, 2023
Publicly Available Date May 19, 2023
Journal Molecular Physics
Print ISSN 0026-8976
Electronic ISSN 1362-3028
Publisher Taylor and Francis
Peer Reviewed Peer Reviewed
Volume 121
Issue 7-8
Article Number e2197081
DOI https://doi.org/10.1080/00268976.2023.2197081
Keywords Phthalocyanine; electroluminescence; van der Waals heterostructure; two dimensional molecular self assembly
Public URL https://nottingham-repository.worktribe.com/output/19465536
Publisher URL https://www.tandfonline.com/doi/full/10.1080/00268976.2023.2197081
Additional Information Memorial Issue for Nick Besley

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