Outputs (134)

Palladium Nanoparticles Hardwired in Carbon Nanoreactors Enable Continually Increasing Electrocatalytic Activity During the Hydrogen Evolution Reaction (2021)
Journal Article

Catalysts typically lose effectiveness during operation, with much effort invested in stabilising active metal centres to prolong their functional lifetime for as long as possible. In this study palladium nanoparticles (PdNP) supported inside hollow... Read More about Palladium Nanoparticles Hardwired in Carbon Nanoreactors Enable Continually Increasing Electrocatalytic Activity During the Hydrogen Evolution Reaction.

Stereochemistry and Twisted Crystals (2021)
Journal Article

This review article discusses a link between stereochemistry and structural and morphological chirality. We present the remarkably frequent, but less often reported, growth of twisted crystals and discuss the reasons for their formation and ways to f... Read More about Stereochemistry and Twisted Crystals.

A ring of grids: a giant spin-crossover cluster (2021)
Journal Article

Mononuclear and icosanuclear spin-crossover complexes, [FeII(HL)2](BF4)2(1) and [FeII 20(L)24](BF4)16(2), were synthesized using an asymmetric multidentate ligand (HL).1has a bis-chelate structure with two protonated ligands, while2has a ring-shape s... Read More about A ring of grids: a giant spin-crossover cluster.

Integrated Multistep Photochemical and Thermal Continuous Flow Reactions: Production of Bicyclic Lactones with Kilogram Productivity (2021)
Journal Article

Combining continuous photochemistry and flow reactions in high-temperature/high-pressure water has enabled us to integrate a multistep sequence into a single process with a reduction in reaction time to 24 h in batch. At the same time, applying this... Read More about Integrated Multistep Photochemical and Thermal Continuous Flow Reactions: Production of Bicyclic Lactones with Kilogram Productivity.

Synthesis of ultrathin rhenium disulfide nanoribbons using nano test tubes (2021)
Journal Article

The synthesis of ultrathin rhenium disulfide (ReS2) nanoribbons within single-walled carbon nanotubes (SWNTs) has been established. Dirhenium decacarbonyl complex is encapsulated into the SWNTs to provide a source of confined rhenium atoms, which rea... Read More about Synthesis of ultrathin rhenium disulfide nanoribbons using nano test tubes.

Continuous‐Flow Synthesis of Orange Emitting Sn(II)‐Doped CsBr Materials (2021)
Journal Article

An ongoing demand toward lead-free all-inorganic cesium metal halide perovskites has presented Sn(II) as an ideal substitute of Pb(II) for applications in optoelectronic devices. The major concern regarding Sn(II) is the instability due to the ambien... Read More about Continuous‐Flow Synthesis of Orange Emitting Sn(II)‐Doped CsBr Materials.

Selective suppression of {112} anatase facets by fluorination for enhanced TiO2 particle size and phase stability at elevated temperatures (2021)
Journal Article

Generally, anatase is the most desirable TiO2 polymorphic phase for photovoltaic and photocatalytic applications due to its higher photoconductivity and lower recombination rates compared to the rutile phase. However, in applications where temperatur... Read More about Selective suppression of {112} anatase facets by fluorination for enhanced TiO2 particle size and phase stability at elevated temperatures.

Experimental measurement and prediction of ionic liquid ionisation energies (2021)
Journal Article

Ionic liquid (IL) valence electronic structure provides key descriptors for understanding and predicting IL properties. The ionisation energies of 60 ILs are measured and the most readily ionised valence state of each IL (the highest occupied molecul... Read More about Experimental measurement and prediction of ionic liquid ionisation energies.

Generation and Characterization of a Library of Novel Biologically Active Functional Surfactants (Surfmers) Using Combined High-Throughput Methods (2021)
Journal Article

We report the first successful combination of three distinct high-throughput techniques to deliver the accelerated design, synthesis, and property screening of a library of novel, bio-instructive, polymeric, comb-graft surfactants. These three-dimens... Read More about Generation and Characterization of a Library of Novel Biologically Active Functional Surfactants (Surfmers) Using Combined High-Throughput Methods.

Organic–Inorganic Hybrid Polyoxotungstates As Configurable Charge Carriers for High Energy Redox Flow Batteries (2021)
Journal Article

We describe the synthesis and electrochemical analysis of the phenyl siloxane-hybridized phosphotungstate Keggin-type polyoxometalate (POM) TBA3[PW11O39(SiC6H5)2O] (TBA3W11SiPh) and its performance as the charge carrier in nonaqueous redox flow batte... Read More about Organic–Inorganic Hybrid Polyoxotungstates As Configurable Charge Carriers for High Energy Redox Flow Batteries.