A ring of grids: a giant spin-crossover cluster

Shiga, Takuya; Tachibana, Minami; Sagayama, Hajime; Kumai, Reiji; Newton, Graham N.; Oshio, Hiroki; Nihei, Masayuki

Abstract

Mononuclear and icosanuclear spin-crossover complexes, [FeII(HL)2](BF4)2(1) and [FeII 20(L)24](BF4)16(2), were synthesized using an asymmetric multidentate ligand (HL).1has a bis-chelate structure with two protonated ligands, while2has a ring-shape structure comprising four [2 × 2] grid moieties and four mononuclear units.

Citation

Shiga, T., Tachibana, M., Sagayama, H., Kumai, R., Newton, G. N., Oshio, H., & Nihei, M. (2021). A ring of grids: a giant spin-crossover cluster. Chemical Communications, 57(79), 10162-10165. https://doi.org/10.1039/d1cc04346c

• Journal Article Type: Article
• Acceptance Date: Sep 6, 2021
• Online Publication Date: Sep 13, 2021
• Publication Date: Oct 11, 2021
• Deposit Date: Jan 31, 2022
• Publicly Available Date: Sep 14, 2022
• Journal: Chemical Communications
• Print ISSN: 1359-7345
• Electronic ISSN: 1364-548X
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 57
• Issue: 79
• Pages: 10162-10165
• DOI: https://doi.org/10.1039/d1cc04346c
• Keywords: Materials Chemistry; Metals and Alloys; Surfaces, Coatings and Films; General Chemistry; Ceramics and Composites; Electronic, Optical and Magnetic Materials; Catalysis
• Public URL: https://nottingham-repository.worktribe.com/output/7353926
• Publisher URL: https://pubs.rsc.org/en/content/articlelanding/2021/CC/D1CC04346C