Outputs (151)

Relationship between karstification and burial dolomitization in Permian platform carbonates (Lower Khuff - Oman) (2016)
Journal Article

Large breccia fabrics associated with karst constitute an important structure in massive limestone successions. The dimensions and shapes of breccia structures are controlled by the initial fracture pattern of the limestone and preferential pathways... Read More about Relationship between karstification and burial dolomitization in Permian platform carbonates (Lower Khuff - Oman).

A new generation of smart amine donors for transaminase-mediated biotransformations (2016)
Journal Article

The application of ω-transaminase biocatalysts for the synthesis of optically pure chiral amines presents a number of challenges, including difficulties associated with displacing the challenging reaction equilibria. Herein, we report a highly effect... Read More about A new generation of smart amine donors for transaminase-mediated biotransformations.

Observation of Binding and Rotation of Methane and Hydrogen within a Functional Metal–Organic Framework (2016)
Journal Article

The key requirement for a portable store of natural gas is to maximize the amount of gas within the smallest possible space. The packing of methane (CH4) in a given storage medium at the highest possible density is, therefore, a highly desirable but... Read More about Observation of Binding and Rotation of Methane and Hydrogen within a Functional Metal–Organic Framework.

Sigmatropic Rearrangement of Vinyl Aziridines: Expedient Synthesis of Cyclic Sulfoximines from Chiral Sulfinimines (2016)
Journal Article

A novel rearrangement of 2-vinyl aziridine 2-carboxylates to unusual chiral cyclic sulfoximines is described herein. The method allows the synthesis of substituted cyclic sulfoximines in high yields with complete stereocontrol, displaying a wide sub... Read More about Sigmatropic Rearrangement of Vinyl Aziridines: Expedient Synthesis of Cyclic Sulfoximines from Chiral Sulfinimines.

Observation of Binding and Rotation of Methane and Hydrogen within a Functional Metal-Organic Framework (2016)
Journal Article

The key requirement for a portable store of natural gas is to maximize the amount of gas within the smallest possible space. The packing of methane (CH4) in a given storage medium at the highest possible density is, therefore, a highly desirable but... Read More about Observation of Binding and Rotation of Methane and Hydrogen within a Functional Metal-Organic Framework.

Uranium Metalla-Allenes with Carbene Imido R2C=UIV=NR′ Units (R=Ph2PNSiMe3; R′=CPh3): Alkali-Metal-Mediated push–pull effects with an Amido Auxiliary (2016)
Journal Article

We report uranium(IV)-carbene-imido-amide metalla-allene complexes [U(BIPMTMS)(NCPh3)(NHCPh3)(M)] (BIPMTMS=C(PPh2NSiMe3)2; M=Li or K) that can be described as R2C=U=NR′ push–pull metalla-allene units, as organometallic counterparts of the well-known... Read More about Uranium Metalla-Allenes with Carbene Imido R2C=UIV=NR′ Units (R=Ph2PNSiMe3; R′=CPh3): Alkali-Metal-Mediated push–pull effects with an Amido Auxiliary.

Freezing the Nonclassical Crystal Growth of a Coordination Polymer Using Controlled Dynamic Gradients (2016)
Journal Article

A methodology that can be efficiently used to synthesize, isolate, and study out‐of‐equilibrium crystal structures employing controlled and diffusion‐limited microfluidic environments is demonstrated. Unlike studies conducted with conventional mixing... Read More about Freezing the Nonclassical Crystal Growth of a Coordination Polymer Using Controlled Dynamic Gradients.

Calculation of high-order virial coefficients for the square-well potential (2016)
Journal Article

Accurate virial coefficients BN(λ,ε) (where ε is the well depth) for the three-dimensional square-well and square-step potentials are calculated for orders N = 5–9 and well widths λ = 1.1−2.0 using a very fast recursive method. The efficiency of the... Read More about Calculation of high-order virial coefficients for the square-well potential.

A Volume Miniaturized Hydrogen Peroxide Sensor Based on Peroxidase Activity of Copper(II) Chlorophyllin on Zinc Oxide and Polypyrrole Nanocomposite (2016)
Journal Article

Measurement of hydrogen peroxide (H2O2) is essential in human physiology and pathology as it provides valuable information with regard to signaling and prognostic of various diseases viz. oxidative stress and cardiovascular diseases. Therefore, we de... Read More about A Volume Miniaturized Hydrogen Peroxide Sensor Based on Peroxidase Activity of Copper(II) Chlorophyllin on Zinc Oxide and Polypyrrole Nanocomposite.

Block copolymer synthesis by controlled/living radical polymerisation in heterogeneous systems (2016)
Journal Article

Nanostructured soft materials open up new opportunities in material design and application, and block copolymer self-assembly is one particularly powerful phenomenon that can be exploited for their synthesis. The advent of controlled/living radical p... Read More about Block copolymer synthesis by controlled/living radical polymerisation in heterogeneous systems.