Outputs (26)

1,8-Bis(silylamido)naphthalene complexes of magnesium and zinc synthesised through alkane elimination reactions (2017)
Journal Article

© The Royal Society of Chemistry. The reactions between magnesium or zinc alkyls and 1,8-bis(triorganosilyl)diaminonaphthalenes afford the 1,8-bis(triorganosilyl)diamidonaphthalene complexes with elimination of alkanes. The reaction between 1,8-C10H6... Read More about 1,8-Bis(silylamido)naphthalene complexes of magnesium and zinc synthesised through alkane elimination reactions.

A monomeric, heterobimetallic complex with an unsupported Mg−Fe bond (2016)
Journal Article

The phosphinimine, trimethylsilyl-substituted BIPM ligand [BIPM = bis(iminophosphorano)methanide] has been used to stabilise CH(Ph2PNSiMe3)2MgFe(η5-C5H5)(CO)2 (1), which is a structurally authenticated complex exhibiting a direct, unsupported bond be... Read More about A monomeric, heterobimetallic complex with an unsupported Mg−Fe bond.

Cyclotrimerisation of isocyanates catalysed by low-coordinate Mn(II) and Fe(II) m-terphenyl complexes (2016)
Journal Article

Two- and three-coordinate m-terphenyl complexes of manganese and iron are efficient catalysts for the selective cyclotrimerisation of primary aliphatic isocyanates affording isocyanurates in short reaction times and under mild conditions.

Alkaline Earth Complexes of a Sterically Demanding Guanidinate Ligand: Alkaline Earth Guanidinate Complexes (2015)
Journal Article

The synthesis of the guanidine MesN{C(NCy2)}N(H)Mes (LH; Mes = 2,4,6-Me3C6H2, Cy = cyclohexyl), and its use as a proligand for the synthesis of alkaline earth metal complexes are reported. Described herein are (i) an unusual Hauser base cubane, (ii)... Read More about Alkaline Earth Complexes of a Sterically Demanding Guanidinate Ligand: Alkaline Earth Guanidinate Complexes.

Tuning coordination in s-block carbazol-9-Yl complexes (2015)
Journal Article

© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. 1,3,6,8-Tetra-tert-butylcarbazol-9-yl and 1,8-diaryl-3,6-di(tert-butyl)carbazol-9-yl ligands have been utilized in the synthesis of potassium and magnesium complexes. The potassium complexes (1,3,6... Read More about Tuning coordination in s-block carbazol-9-Yl complexes.

Ligand influences on homoleptic Group 12 m-terphenyl complexes (2014)
Journal Article

Three m-terphenyl ligands 2,6-Ar2C6H3 – [Ar = 2,6-Me2C6H3 (2,6-Xyl); 3,5-Me2C6H3 (3,5-Xyl); 2,3,4,5,6-Me5C6 (Pmp)] have been used to stabilise three series of two-coordinate Group 12 diaryl complexes; (2,6-Ar2C6H3)2M [M = Zn, Cd, Hg; Ar = 2,6-Xyl 1-3... Read More about Ligand influences on homoleptic Group 12 m-terphenyl complexes.