A Domino Radical Amidation/Semipinacol Approach to All-Carbon Quaternary Centers Bearing an Aminomethyl Group
(2023)
Journal Article
Dhak, M. S., Arunprasath, D., Argent, S. P., & Cuthbertson, J. D. (2023). A Domino Radical Amidation/Semipinacol Approach to All-Carbon Quaternary Centers Bearing an Aminomethyl Group. Chemistry - A European Journal, 29(47), Article e202300922. https://doi.org/10.1002/chem.202300922
A photoredox-mediated radical amidation ring-expansion sequence that enables the generation of all-carbon quaternary centers bearing a protected aminomethyl substituent is described. The methodology can be applied to both styrene and unactivated alke... Read More about A Domino Radical Amidation/Semipinacol Approach to All-Carbon Quaternary Centers Bearing an Aminomethyl Group.