Phosphorus derivatives of mesoionic carbenes: synthesis and characterization of triazaphosphole-5-ylidene → BF 3 adducts † ‡
(2023)
Journal Article
Dettling, L., Limberg, N., Küppers, R., Frost, D., Weber, M., Coles, N. T., …Müller, C. (in press). Phosphorus derivatives of mesoionic carbenes: synthesis and characterization of triazaphosphole-5-ylidene → BF 3 adducts † ‡. Chemical Communications, 59(68), 10243-10246. https://doi.org/10.1039/d3cc03268j
Trimethylsilyl-substituted triazaphospholes were synthesized by a [3+2] cycloaddition reaction between organic azides and (CH3)3Si-C ≡ P. In an attempt to isolate their N-alkylated products, the formation of BF3 adducts of unprecedented triazaphospho... Read More about Phosphorus derivatives of mesoionic carbenes: synthesis and characterization of triazaphosphole-5-ylidene → BF 3 adducts † ‡.