All Outputs (2)

Hydride Abstraction and Deprotonation - an Efficient Route to Low Coordinate Phosphorus and Arsenic Species (2015)
Journal Article
Taylor, L. J., Bühl, M., Wawrzyniak, P., Chalmers, B. A., Woollins, J. D., Slawin, A. M., …Kilian, P. (2016). Hydride Abstraction and Deprotonation - an Efficient Route to Low Coordinate Phosphorus and Arsenic Species. European Journal of Inorganic Chemistry, 2016(5), 659-666. https://doi.org/10.1002/ejic.201500948

Treatment of Acenap(PiPr2)(EH2) (Acenap = acenaphthene-5,6-diyl; 1a, E = As; 1b, E = P) with Ph3C·BF4 resulted in hydride abstraction to give [Acenap(PiPr2)(EH)][BF4] (2a, E = As; 2b, E = P). These represent the first structurally characterised phosp... Read More about Hydride Abstraction and Deprotonation - an Efficient Route to Low Coordinate Phosphorus and Arsenic Species.

Spontaneous Dehydrocoupling in Peri-Substituted Phosphine-Borane Adducts (2015)
Journal Article
Taylor, L. J., Surgenor, B. A., Wawrzyniak, P., Ray, M. J., Cordes, D. B., Slawin, A. M., & Kilian, P. (2016). Spontaneous Dehydrocoupling in Peri-Substituted Phosphine-Borane Adducts. Dalton Transactions, 45(5), 1976–1986. https://doi.org/10.1039/C5DT02539G