All Outputs (2)

Dealkanative Main Group Couplings across the peri-Gap (2017)
Journal Article
Taylor, L. J., Bühl, M., Chalmers, B. A., Ray, M. J., Wawrzyniak, P., Walton, J. C., …Kilian, P. (2017). Dealkanative Main Group Couplings across the peri-Gap. Journal of the American Chemical Society, 139(51), 18545-18551. https://doi.org/10.1021/jacs.7b08682

Here, we highlight the ability of peri-substitution chemistry to promote a series of unique P-P/P-As coupling reactions, which proceed with concomitant C-H bond formation. This dealkanative reactivity represents an interesting and unexpected expansio... Read More about Dealkanative Main Group Couplings across the peri-Gap.

Optimised synthesis and characterisation of 1-adamantyltrimethylphosphonium iodide (2017)
Journal Article
Mansour, R., Nejman, P. S., Taylor, L. J., Chalmers, B. A., Rey, F., Bengueddach, A., …Kilian, P. (2017). Optimised synthesis and characterisation of 1-adamantyltrimethylphosphonium iodide. Polyhedron, 133, 302-306. https://doi.org/10.1016/j.poly.2017.05.050

A synthetic route to multigram quantities of 1-adamantyltrimethylphosphonium iodide is reported. The synthesis starts from the commercially available precursor 1-adamantyl bromide and was optimised with respect to yield and ease of purification. The... Read More about Optimised synthesis and characterisation of 1-adamantyltrimethylphosphonium iodide.