An efficient, scalable synthesis of ferrocenylphosphine and dichloroferrocenylphosphine
(2016)
Journal Article
Surgenor, B. A., Taylor, L. J., Nordheider, A., Slawin, A. M., Athukorala Arachchige, K. S., Woollins, J. D., & Kilian, P. (2016). An efficient, scalable synthesis of ferrocenylphosphine and dichloroferrocenylphosphine. RSC Advances, 6(7), 5973-5976. https://doi.org/10.1039/C5RA27594F
All Outputs (25)
Hydride Abstraction and Deprotonation - an Efficient Route to Low Coordinate Phosphorus and Arsenic Species (2015)
Journal Article
Taylor, L. J., Bühl, M., Wawrzyniak, P., Chalmers, B. A., Woollins, J. D., Slawin, A. M., …Kilian, P. (2016). Hydride Abstraction and Deprotonation - an Efficient Route to Low Coordinate Phosphorus and Arsenic Species. European Journal of Inorganic Chemistry, 2016(5), 659-666. https://doi.org/10.1002/ejic.201500948Treatment of Acenap(PiPr2)(EH2) (Acenap = acenaphthene-5,6-diyl; 1a, E = As; 1b, E = P) with Ph3C·BF4 resulted in hydride abstraction to give [Acenap(PiPr2)(EH)][BF4] (2a, E = As; 2b, E = P). These represent the first structurally characterised phosp... Read More about Hydride Abstraction and Deprotonation - an Efficient Route to Low Coordinate Phosphorus and Arsenic Species.
Spontaneous Dehydrocoupling in Peri-Substituted Phosphine-Borane Adducts (2015)
Journal Article
Taylor, L. J., Surgenor, B. A., Wawrzyniak, P., Ray, M. J., Cordes, D. B., Slawin, A. M., & Kilian, P. (2016). Spontaneous Dehydrocoupling in Peri-Substituted Phosphine-Borane Adducts. Dalton Transactions, 45(5), 1976–1986. https://doi.org/10.1039/C5DT02539G
Synthetic and Structural Study of the Coordination Chemistry of a peri-Backbone-Supported Phosphino-phosphonium Salt (2014)
Journal Article
Ray, M. J., Bühl, M., Taylor, L. J., Athukorala Arachchige, K. S., Slawin, A. M., & Kilian, P. (2014). Synthetic and Structural Study of the Coordination Chemistry of a peri-Backbone-Supported Phosphino-phosphonium Salt. Inorganic Chemistry, 53(16), 8538–8547. https://doi.org/10.1021/ic501142v
On the control of secondary carbanion structure utilising ligand effects during directed metallation (2012)
Journal Article
Wheatley, A. E., Clayden, J., Hillier, I. H., Campbell Smith, A., Vincent, M. A., Taylor, L. J., & Haywood, J. (2012). On the control of secondary carbanion structure utilising ligand effects during directed metallation. Beilstein Journal of Organic Chemistry, 8, 50-60. https://doi.org/10.3762/bjoc.8.5N,N-Diisopropyl-2-propylbenzamide 6-H undergoes lateral deprotonation by t-BuLi in the presence of the Lewis base PMDTA (N,N,N′,N″,N″-pentamethyldiethylenetriamine) to give a benzyllithium 6-Lil·PMDTA that incorporates a trigonal planar secondary car... Read More about On the control of secondary carbanion structure utilising ligand effects during directed metallation.