The alteration of intra-ligand donor-acceptor interactions through torsional connectivity in substituted Re-dppz complexes

Adams, Bethany; Shillito, Georgina E.; Salm, Holly van der; Horvath, Raphael; Larsen, Christopher B.; Sun,  Xue-Zhong; Lucas, Nigel T.; George, Michael W.; Gordon, Keith C.

doi:10.1021/acs.inorgchem.7b01710

All Outputs (4)

Probing the carbon-hydrogen activation of alkanes following photolysis of Tp’Rh(CNR)(carbodiimide): a computational and time-resolved infrared spectroscopic study (2017)
Journal Article

Carbon–hydrogen bond activation reactions of alkanes by Tp’Rh(CNR) (Tp’ = Tp = trispyrazolylborate or Tp* = tris(3,5-dimethylpyrazolyl)borate) were followed by timeresolved infrared spectroscopy (TRIR) in the υ(CNR) and υ(BH) spectral regions on Tp*R... Read More about Probing the carbon-hydrogen activation of alkanes following photolysis of Tp’Rh(CNR)(carbodiimide): a computational and time-resolved infrared spectroscopic study.

Additive manufacture of complex 3D Au-containing nanocomposites by simultaneous two-photon polymerisation and photoreduction (2017)
Journal Article

© 2017 The Author(s). The fabrication of complex three-dimensional gold-containing nanocomposite structures by simultaneous two-photon polymerisation and photoreduction is demonstrated. Increased salt delivers reduced feature sizes down to line width... Read More about Additive manufacture of complex 3D Au-containing nanocomposites by simultaneous two-photon polymerisation and photoreduction.

Thionated naphthalene diimides: tuneable chromophores for applications in photoactive dyads (2017)
Journal Article

Varying the degree of thionation of a series of naphthalene diimide (NDI) and naphthalic imides (NI) phenothiazine dyad systems afford a systematic approach for tuning of the system’s donor-acceptor energy gap. Each dyad was compared to model NDI/NI... Read More about Thionated naphthalene diimides: tuneable chromophores for applications in photoactive dyads.

The alteration of intra-ligand donor-acceptor interactions through torsional connectivity in substituted Re-dppz complexes (2017)
Journal Article

The ground and excited properties of a series of [ReCl(CO)3(dppz)] complexes with substituted donor groups have been investigated. Alteration of donor-acceptor communication through modulation of torsional angle and the number and nature of the donor... Read More about The alteration of intra-ligand donor-acceptor interactions through torsional connectivity in substituted Re-dppz complexes.