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Thermal degradation of polyvinyl chloride in the presence of lead oxide: A kinetic and mechanistic investigation (2024)
Journal Article

The elimination of toxic heavy metals from metallurgical wastes before its recycling to steel furnaces is essential. Lead oxide (PbO) is a major toxic heavy metal present in electric arc furnace dust (EAFD). The co-recycling of EAFD with Polyvinyl ch... Read More about Thermal degradation of polyvinyl chloride in the presence of lead oxide: A kinetic and mechanistic investigation.

Solving the microwave heating uniformity conundrum for scalable high-temperature processes via a toroidal fluidised-bed reactor (2024)
Journal Article

Challenges exist to implementing high-temperature microwave processes with changing dielectric properties that achieve uniform processing. This paper presents a new high-temperature hybrid microwave processing system which overcomes these challenges... Read More about Solving the microwave heating uniformity conundrum for scalable high-temperature processes via a toroidal fluidised-bed reactor.

Chlorine Fixing Ability of Electric Arc Furnace Dust During the Thermal Degradation of Polyvinyl Chloride under Oxidative Conditions (2023)
Journal Article

Electric arc furnace dust (EAFD) and polyvinyl chloride (PVC) are two hazardous wastes that are accumulated world-wide at an alarming rate. Utilising these two wastes simultaneously towards a sustainable recycling loop can greatly mitigate their envi... Read More about Chlorine Fixing Ability of Electric Arc Furnace Dust During the Thermal Degradation of Polyvinyl Chloride under Oxidative Conditions.

A thermo-kinetic investigation on the thermal degradation of polyvinyl chloride in the presence of magnetite and hematite (2022)
Journal Article

Electric arc furnace dust (EAFD) which is accumulated in large amounts world-wide contains hematite (Fe2O3) and significant quantities of magnetite (Fe3O4). Waste polyvinyl chloride (PVC) also poses a great environmental threat aside to accumulated E... Read More about A thermo-kinetic investigation on the thermal degradation of polyvinyl chloride in the presence of magnetite and hematite.

Thermodynamic, pyrolytic, and kinetic investigation on the thermal decomposition of polyvinyl chloride in the presence of franklinite (2022)
Journal Article

Thermal co-treatment of Electric Arc Furnace Dust (EAFD) and polyvinyl chloride (PVC) may provide a viable route for reprocessing these hazardous materials within the circular economy. To develop and optimise a commercial treatment process, the compl... Read More about Thermodynamic, pyrolytic, and kinetic investigation on the thermal decomposition of polyvinyl chloride in the presence of franklinite.

Leaching behavior of zinc and lead from electric arc furnace dust – Poly(vinyl) chloride residues after oxidative thermal treatment (2021)
Journal Article

Oxidative thermal treatment of electric arc furnace dust (EAFD) mixed with poly(vinyl) chloride (PVC) was carried out to study the impact of oxidizing environment on the extraction of valuable metals. The effect of oxygen partial pressure, temperatur... Read More about Leaching behavior of zinc and lead from electric arc furnace dust – Poly(vinyl) chloride residues after oxidative thermal treatment.

Microwave selective heating of electric arc furnace dust constituents toward sustainable recycling: Contribution of electric and magnetic fields (2021)
Journal Article

Microwave heating of waste electric arc furnace dust (EAFD) for the purpose of its remediation has been studied extensively. However, these studies considered EAFD as a bulk material without addressing either the relative response of its individual c... Read More about Microwave selective heating of electric arc furnace dust constituents toward sustainable recycling: Contribution of electric and magnetic fields.

Methodology for the synthesis of methacrylate monomers using designed single mode microwave applicators (2019)
Journal Article

© 2019 The Royal Society of Chemistry. A novel single-well prototype high throughput microwave reactor geometry has been produced and shown to be capable of synthesizing an array of non-commercially available methacrylate monomers. The reactor, which... Read More about Methodology for the synthesis of methacrylate monomers using designed single mode microwave applicators.

Microwave pyrolysis of pecan nut shell and thermogravimetric, textural and spectroscopic characterization of carbonaceous products (2018)
Journal Article

In the present work, the pyrolysis of pecan nut shell was studied using microwave technology at different input power and exposure time. The carbonaceous products were characterized using elemental analysis, potentiometric titration, thermogravimetri... Read More about Microwave pyrolysis of pecan nut shell and thermogravimetric, textural and spectroscopic characterization of carbonaceous products.

Realising the environmental benefits of metal–organic frameworks: recent advances in microwave synthesis (2018)
Journal Article

Metal–organic frameworks (MOFs) are a broad class of porous crystalline materials that show great potential for a wide-range of applications in areas such as energy and environmental sustainability. MOFscan show significant advantages in gas selectiv... Read More about Realising the environmental benefits of metal–organic frameworks: recent advances in microwave synthesis.

Thermal analysis on the pyrolysis of tetrabromobisphenol A (TBBPA) and Electric Arc Furnace Dust mixtures (2017)
Journal Article

The pyrolysis of Tetrabromobisphenol A (TBBPA) mixed with Electric Arc Furnace Dust (EAFD) was studied using thermogravimetric analysis (TGA) and theoretically analysed using thermodynamic equilibrium calculations. Mixtures of both materials with var... Read More about Thermal analysis on the pyrolysis of tetrabromobisphenol A (TBBPA) and Electric Arc Furnace Dust mixtures.

Microwave treatment of electric arc furnace dust with Tetrabromobisphenol A: Dielectric characterization and pyrolysis-leaching (2017)
Journal Article

In the present work microwave treatment of electric arc furnace dust (EAFD) mixed with tetrabromobisphenol A (TBBPA) was investigated. A range of characterization techniques were used to understand the thermal behaviour of TBBPA-EAFD mixtures under m... Read More about Microwave treatment of electric arc furnace dust with Tetrabromobisphenol A: Dielectric characterization and pyrolysis-leaching.