All Outputs (4)

Phospholenes from Phosphabenzenes by Selective Ring Contraction (2022)
Journal Article

A 3-amino-functionalized phosphabenzene (phosphinine) has been synthesized and structurally characterized. The pyramidalized nitrogen atom of the dimethylamino substituent indicates only a weak interaction between the lone pair of the nitrogen atom a... Read More about Phospholenes from Phosphabenzenes by Selective Ring Contraction.

Reactivity of Sodium Pentaphospholide Na[cyclo ‐P 5] towards C≡E (E=C, N, P) Triple Bonds (2022)
Journal Article

A diglyme solution of Na[cyclo-P5] (1) reacts with alkynes and isolobal nitriles and phosphaalkynes to afford the otherwise elusive (aza)phospholide anions 2 a–c, 4 a,b, and 6. The reaction of Na[cyclo-P5] with alkynes and nitriles was studied by mea... Read More about Reactivity of Sodium Pentaphospholide Na[cyclo ‐P 5] towards C≡E (E=C, N, P) Triple Bonds.

Triple dehydrofluorination as a route to amidine-functionalized, aromatic phosphorus heterocycles (2022)
Journal Article

Hitherto unknown amidine-functionalized phosphabenzenes selectively form by a cascade of dehydrofluorination reactions.

Borane Adducts of Aromatic Phosphorus Heterocycles: Synthesis, Crystallographic Characterization and Reactivity of a Phosphinine‐B(C 6 F 5 ) 3 Lewis Pair (2022)
Journal Article

A phosphinine-borane adduct of a Me3Si-functionalized phosphinine and the Lewis acid B(C6F5)3 has been synthesized and characterized crystallographically for the first time. The reaction strongly depends on the nature of the substituents in the α-pos... Read More about Borane Adducts of Aromatic Phosphorus Heterocycles: Synthesis, Crystallographic Characterization and Reactivity of a Phosphinine‐B(C 6 F 5 ) 3 Lewis Pair.