All Outputs (3)

Slow magnetic relaxation in Fe(ii) m-terphenyl complexes (2022)
Journal Article
Valentine, A. J., Geer, A. M., Blundell, T. J., Tovey, W., Cliffe, M. J., Davies, E. S., …Kays, D. L. (2022). Slow magnetic relaxation in Fe(ii) m-terphenyl complexes. Dalton Transactions, 51(47), 18118-18126. https://doi.org/10.1039/d2dt03531f

Two-coordinate transition metal complexes are exciting candidates for single-molecule magnets (SMMs) because their highly axial coordination environments lead to sizeable magnetic anisotropy. We report a series of five structurally related two-coordi... Read More about Slow magnetic relaxation in Fe(ii) m-terphenyl complexes.

Tethering Effects in Oligomer-Based Metal-Organic Frameworks (2022)
Journal Article
Dodson, R. A., Park, J., Kim, J., Cliffe, M. J., & Cohen, S. M. (2022). Tethering Effects in Oligomer-Based Metal-Organic Frameworks. Inorganic Chemistry, 61(31), 12063-12488. https://doi.org/10.1021/acs.inorgchem.2c01567

Metal-organic frameworks (MOFs) can be constructed using conventional molecular linkers or polymeric linkers (polyMOFs), but the relationship and relative properties of these related materials remain understudied. As an intermediate between these two... Read More about Tethering Effects in Oligomer-Based Metal-Organic Frameworks.

Magnetic order in a metal thiocyanate perovskite-analogue (2022)
Journal Article
Cliffe, M. J., Fabelo, O., & Cañadillas-Delgado, L. (2022). Magnetic order in a metal thiocyanate perovskite-analogue. CrystEngComm, https://doi.org/10.1039/d2ce00649a

Metal thiocyanate perovskite-analogues are a growing class of materials, but although they contain paramagnetic cations there have been no reports of their magnetic properties. Due to the large separations between the paramagnetic cations, with a sho... Read More about Magnetic order in a metal thiocyanate perovskite-analogue.