All Outputs (3)

Magnetic order in a metal thiocyanate perovskite-analogue (2022)
Journal Article
Cliffe, M. J., Fabelo, O., & Cañadillas-Delgado, L. (2022). Magnetic order in a metal thiocyanate perovskite-analogue. CrystEngComm, https://doi.org/10.1039/d2ce00649a

Metal thiocyanate perovskite-analogues are a growing class of materials, but although they contain paramagnetic cations there have been no reports of their magnetic properties. Due to the large separations between the paramagnetic cations, with a sho... Read More about Magnetic order in a metal thiocyanate perovskite-analogue.

Direct imaging of correlated defect nanodomains in a metal-organic framework (2020)
Journal Article
Johnstone, D. N., Firth, F. C., Grey, C. P., Midgley, P. A., Cliffe, M. J., & Collins, S. M. (2020). Direct imaging of correlated defect nanodomains in a metal-organic framework. Journal of the American Chemical Society, 142(30), 13081–13089. https://doi.org/10.1021/jacs.0c04468

Defect engineering can enhance key properties of metal-organic frameworks (MOFs). Tailoring the distribution of defects, for example in correlated nanodomains, requires characterization across length scales. However, a critical na-noscale characteriz... Read More about Direct imaging of correlated defect nanodomains in a metal-organic framework.

Ground and Excited States of Bis?4?Methoxybenzyl?Substituted Diketopyrrolopyrroles: Spectroscopic and Electrochemical Studies (2019)
Journal Article
Murphy, A. S., Killalea, C. E., Humphreys, J., Hume, P. A., Cliffe, M. J., Murray, G. J., …Amabilino, D. B. (2019). Ground and Excited States of Bis‐4‐Methoxybenzyl‐Substituted Diketopyrrolopyrroles: Spectroscopic and Electrochemical Studies. ChemPlusChem, 84(9), 1413-1422. https://doi.org/10.1002/cplu.201900286

A series of symmetrically bis?4?methoxybenzyl (4MB) N?substituted 1,4?diketopyrrolo[3,4?c]pyrrole (DPP) derivatives have been synthesized. The 4MB unit makes the DPP core soluble, and shows subtle modification of up to 0.2?eV in ground and excited st... Read More about Ground and Excited States of Bis?4?Methoxybenzyl?Substituted Diketopyrrolopyrroles: Spectroscopic and Electrochemical Studies.