Gold-catalyzed oxidative coupling of arylsilanes and arenes: Origin of selectivity and improved precatalyst
(2013)
Journal Article
The mechanism of gold-catalyzed coupling of arenes with aryltrimethylsilanes has been investigated, employing an improved precatalyst (thtAuBr3) to facilitate kinetic analysis. In combination with linear free-energy relationships, kinetic isotope eff... Read More about Gold-catalyzed oxidative coupling of arylsilanes and arenes: Origin of selectivity and improved precatalyst.