Synthesis and Structural Studies of peri-Substituted Acenaphthenes with Tertiary Phosphine and Stibine Groups

Taylor, Laurence J.; Lawson, Emma E.; Cordes, David B.; Athukorala Arachchige, Kasun S.; Slawin, Alexandra M. Z.; Chalmers, Brian A.; Kilian, Petr

doi:10.3390/molecules29081841

All Outputs (2)

Mechanistic investigations of the Fe(ii) mediated synthesis of squaraines (2024)
Journal Article

The scission and homologation of CO is a fundamental process in the Fischer–Tropsch reaction. However, given the heterogeneous nature of the catalyst and forcing reaction conditions, it is difficult to determine the intermediates of this reaction. He... Read More about Mechanistic investigations of the Fe(ii) mediated synthesis of squaraines.

Synthesis and Structural Studies of peri-Substituted Acenaphthenes with Tertiary Phosphine and Stibine Groups (2024)
Journal Article

Two mixed peri-substituted phosphine-chlorostibines, Acenap(PiPr2)(SbPhCl) and Acenap(PiPr2)(SbCl2) (Acenap = acenaphthene-5,6-diyl) reacted cleanly with Grignard reagents or nBuLi to give the corresponding tertiary phosphine-stibines Acenap(PiPr2)(S... Read More about Synthesis and Structural Studies of peri-Substituted Acenaphthenes with Tertiary Phosphine and Stibine Groups.