U-III{N(SiMe(2)tBu)(2)}(3) : A Structurally Authenticated Trigonal Planar Actinide Complex
(2014)
Journal Article
All Outputs (6)
Two-Electron Reductive Carbonylation of Terminal Uranium(V) and Uranium(VI) Nitrides to Cyanate by Carbon Monoxide (2014)
Journal Article
Two-electron reductive carbonylation of the uranium(VI) nitride [U(TrenTIPS)(N)] (2, TrenTIPS=N(CH2CH2NSiiPr3)3) with CO gave the uranium(IV) cyanate [U(TrenTIPS)(NCO)] (3). KC8 reduction of 3 resulted in cyanate dissociation to give [U(TrenTIPS)] (4... Read More about Two-Electron Reductive Carbonylation of Terminal Uranium(V) and Uranium(VI) Nitrides to Cyanate by Carbon Monoxide.
Synthesis, Characterization, and Reactivity of a Uranium(VI) Carbene Imido Oxo Complex (2014)
Journal Article
We report the uranium(VI) carbene imido oxo complex [U(BIPMTMS)(NMes)(O)(DMAP)2] (5, BIPMTMS=C(PPh2NSiMe3)2; Mes=2,4,6-Me3C6H2; DMAP=4-(dimethylamino)pyridine) which exhibits the unprecedented arrangement of three formal multiply bonded ligands to on... Read More about Synthesis, Characterization, and Reactivity of a Uranium(VI) Carbene Imido Oxo Complex.
Photochemical Dihydrogen Production Using an Analogue of the Active Site of [NiFe] Hydrogenase (2014)
Journal Article
The photoproduction of dihydrogen (H2) by a low molecular weight analogue of the active site of [NiFe] hydrogenase has been investigated by the reduction of the [NiFe2] cluster, 1, by a photosensitier PS (PS = [ReCl(CO)3(bpy)] or [Ru(bpy)3][PF6]2). R... Read More about Photochemical Dihydrogen Production Using an Analogue of the Active Site of [NiFe] Hydrogenase.
Synthesis and Characterization of an f-Block Terminal Parent Imido [U?NH] Complex: A Masked Uranium(IV) Nitride (2014)
Journal Article
Deprotonation of [U(TrenTIPS)(NH2)] (1) [TrenTIPS = N(CH2CH2NSiPri3)3] with organoalkali metal reagents MR (M = Li, R = But; M = Na?Cs, R = CH2C6H5) afforded the imido-bridged dimers [{U-(TrenTIPS)(?-N[H]M)}2] [M = L ?Cs (2a?e)]. Treatmentof 2c (M =... Read More about Synthesis and Characterization of an f-Block Terminal Parent Imido [U?NH] Complex: A Masked Uranium(IV) Nitride.
Triamidoamine-Uranium(IV)-Stabilized Terminal Parent Phosphide and Phosphinidene Complexes (2014)
Journal Article
Reaction of [U(TrenTIPS)(THF)][BPh4] (1; TrenTIPS=N{CH2CH2NSi(iPr)3}3) with NaPH2 afforded the novel f-block terminal parent phosphide complex [U(TrenTIPS)(PH2)] (2; U–P=2.883(2) Å). Treatment of 2 with one equivalent of KCH2C6H5 and two equivalents... Read More about Triamidoamine-Uranium(IV)-Stabilized Terminal Parent Phosphide and Phosphinidene Complexes.