Substituent dependence on the spin crossover behaviour of mononuclear Fe(ii) complexes with asymmetric tridentate ligands

Saiki, Ryo; Miyamoto, Haruka; Sagayama, Hajime; Kumai, Reiji; Newton, Graham N.; Shiga, Takuya; Oshio, Hiroki

doi:10.1039/c9dt00204a

All Outputs (5)

Asymmetric Hybrid Polyoxometalates: A Platform for Multifunctional Redox‐Active Nanomaterials (2019)
Journal Article

Access to asymmetrically functionalised polyoxometalates is a grand challenge as it could lead to new molecular nanomaterials with multiple or modular functionality. Here, a simple “one-pot” synthetic approach to the isolation of an asymmetrically fu... Read More about Asymmetric Hybrid Polyoxometalates: A Platform for Multifunctional Redox‐Active Nanomaterials.

Host–Guest Hybrid Redox Materials Self‐Assembled from Polyoxometalates and Single‐Walled Carbon Nanotubes (2019)
Journal Article

The development of next‐generation molecular‐electronic, electrocatalytic, and energy‐storage systems depends on the availability of robust materials in which molecular charge‐storage sites and conductive hosts are in intimate contact. It is shown he... Read More about Host–Guest Hybrid Redox Materials Self‐Assembled from Polyoxometalates and Single‐Walled Carbon Nanotubes.

A Brønsted‐Ligand‐Based Iron Complex as a Molecular Switch with Five Accessible States (2019)
Journal Article

A Brønsted ligand molecular switch with five accessible states (2019)
Journal Article

A mononuclear Fe(II) complex, prepared with a Brønsted diacid ligand, H2L (H2L = 2-[5-phenyl-1H-pyrazole-3-yl] 6benzimidazole pyridine), shows switchable physical properties and was isolated in five different electronic states. The spin crossover (SC... Read More about A Brønsted ligand molecular switch with five accessible states.

Substituent dependence on the spin crossover behaviour of mononuclear Fe(ii) complexes with asymmetric tridentate ligands (2019)
Journal Article

Three mononuclear iron(II) complexes of the formula [FeII(H2L1-3)2](BF4)2.x(solv.) (H2L1-3 = 2-[5-(R-phenyl)-1H-pyrazole-3-yl] 6-benzimidazole pyridine; H2L1: R = 4-methylphenyl, H2L2, R = 2,4,6-trimethylphenyl, H2L3, R = 2,3,4,5,6pentamethylphenyl)... Read More about Substituent dependence on the spin crossover behaviour of mononuclear Fe(ii) complexes with asymmetric tridentate ligands.