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Tuning the electronic environment of the anion by using binary ionic liquid mixtures

Men, Shuang; Licence, Peter

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Authors

Shuang Men



Abstract

The electronic environment of the anion is tuned by using binary ionic liquid mixtures employing a com- mon anion and two cations with large difference in acidity. X-ray photoelectron spectroscopy is used to monitor the change of the electronic environment of the anion by measuring the binding energy of elements present in the anion. It is found that due to the large difference in acidity of the two cations, noticeable shifts can be observed for all anion-based components, no matter how basic the anion is.

Citation

Men, S., & Licence, P. (2017). Tuning the electronic environment of the anion by using binary ionic liquid mixtures. Chemical Physics Letters, 681, https://doi.org/10.1016/j.cplett.2017.05.049

Journal Article Type Article
Acceptance Date May 17, 2017
Online Publication Date May 18, 2017
Publication Date Aug 1, 2017
Deposit Date Sep 7, 2017
Publicly Available Date Mar 29, 2024
Journal Chemical Physics Letters
Print ISSN 0009-2614
Electronic ISSN 0009-2614
Publisher Elsevier
Peer Reviewed Peer Reviewed
Volume 681
DOI https://doi.org/10.1016/j.cplett.2017.05.049
Keywords Binary ionic liquid mixtures, Anion, XPS, Anion-based components
Public URL https://nottingham-repository.worktribe.com/output/875737
Publisher URL http://www.sciencedirect.com/science/article/pii/S0009261417304967

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