Solvent-induced on/off switching of intramolecular electron transfer in a cyanide-bridged trigonal bipyramidal complex

Wei, Rong Jia; Nakahara, Ryohei; Cameron, Jamie M.; Newton, Graham; Shiga, Takuya; Sagayama, Hajime; Kumai, Reiji; Murakami, Youichi; Oshio, Hiroki

Abstract

A cyanide-bridged [Co3Fe2] cluster with trigonal bipyramidal geometry shows solvent-driven reversible on/off switching of its thermally induced electron-transfer-coupled spin transition (ETCST) behaviour.

Citation

Wei, R. J., Nakahara, R., Cameron, J. M., Newton, G., Shiga, T., Sagayama, H., …Oshio, H. (2016). Solvent-induced on/off switching of intramolecular electron transfer in a cyanide-bridged trigonal bipyramidal complex. Dalton Transactions, 45(43), 17104-17107. https://doi.org/10.1039/C6DT03416K

• Journal Article Type: Article
• Acceptance Date: Oct 12, 2016
• Online Publication Date: Oct 19, 2016
• Publication Date: Oct 19, 2016
• Deposit Date: Nov 29, 2016
• Publicly Available Date: Nov 29, 2016
• Journal: Dalton Transactions
• Print ISSN: 1477-9226
• Electronic ISSN: 1477-9234
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 45
• Issue: 43
• Pages: 17104-17107
• DOI: https://doi.org/10.1039/C6DT03416K
• Public URL: http://eprints.nottingham.ac.uk/id/eprint/38666
• Publisher URL: http://pubs.rsc.org/en/Content/ArticleLanding/2016/DT/C6DT03416K#!divAbstract
• Copyright Statement: Copyright information regarding this work can be found at the following address: http://eprints.nottingham.ac.uk/end_user_agreement.pdf