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Solvent-induced on/off switching of intramolecular electron transfer in a cyanide-bridged trigonal bipyramidal complex

Wei, Rong Jia; Nakahara, Ryohei; Cameron, Jamie M.; Newton, Graham; Shiga, Takuya; Sagayama, Hajime; Kumai, Reiji; Murakami, Youichi; Oshio, Hiroki

Authors

Rong Jia Wei

Ryohei Nakahara

Takuya Shiga

Hajime Sagayama

Reiji Kumai

Youichi Murakami

Hiroki Oshio



Abstract

A cyanide-bridged [Co3Fe2] cluster with trigonal bipyramidal geometry shows solvent-driven reversible on/off switching of its thermally induced electron-transfer-coupled spin transition (ETCST) behaviour.

Citation

Wei, R. J., Nakahara, R., Cameron, J. M., Newton, G., Shiga, T., Sagayama, H., …Oshio, H. (2016). Solvent-induced on/off switching of intramolecular electron transfer in a cyanide-bridged trigonal bipyramidal complex. Dalton Transactions, 45(43), 17104-17107. https://doi.org/10.1039/C6DT03416K

Journal Article Type Article
Acceptance Date Oct 12, 2016
Online Publication Date Oct 19, 2016
Publication Date Oct 19, 2016
Deposit Date Nov 29, 2016
Publicly Available Date Nov 29, 2016
Journal Dalton Transactions
Print ISSN 1477-9226
Electronic ISSN 1477-9234
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 45
Issue 43
Pages 17104-17107
DOI https://doi.org/10.1039/C6DT03416K
Public URL http://eprints.nottingham.ac.uk/id/eprint/38666
Publisher URL http://pubs.rsc.org/en/Content/ArticleLanding/2016/DT/C6DT03416K#!divAbstract
Copyright Statement Copyright information regarding this work can be found at the following address: http://eprints.nottingham.ac.uk/end_user_agreement.pdf

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Copyright Statement
Copyright information regarding this work can be found at the following address: http://eprints.nottingham.ac.uk/end_user_agreement.pdf





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