Thionated perylene diimides with intense absorbance in the near-IR

Llewellyn, Ben A.; Davies, Stephen E.; Pfeiffer, Constance R.; Cooper, Mick; Lewis, William; Champness, Neil R.

Abstract

A synthetic strategy involving a combination of tetra-thionation and amine substitution in the bay region of a perylene diimide (PDI) leads to remarkable examples of neutral PDIs with intense absorption maxima in the near infrared. Generation of the corresponding monoanions red shifts the absorption profile to give short-wavelength infrared bands.

Citation

Llewellyn, B. A., Davies, S. E., Pfeiffer, C. R., Cooper, M., Lewis, W., & Champness, N. R. (2015). Thionated perylene diimides with intense absorbance in the near-IR. Chemical Communications, https://doi.org/10.1039/C5CC09962E

• Journal Article Type: Article
• Acceptance Date: Dec 15, 2015
• Publication Date: Dec 15, 2015
• Deposit Date: Jan 4, 2016
• Publicly Available Date: Jan 4, 2016
• Journal: Chemical Communications
• Print ISSN: 1359-7345
• Electronic ISSN: 1364-548X
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• DOI: https://doi.org/10.1039/C5CC09962E
• Public URL: https://nottingham-repository.worktribe.com/output/769340
• Publisher URL: http://pubs.rsc.org/en/Content/ArticleLanding/2016/CC/C5CC09962E#!divAbstract
• Contract Date: Jan 4, 2016