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Isolation of stable non cyclic 1,2-disulfoxides: revisiting the thermolysis of S-aryl sulfinimines

Souto, Jos� A.; Lewis, William; Stockman, Robert A.

Isolation of stable non cyclic 1,2-disulfoxides: revisiting the thermolysis of S-aryl sulfinimines Thumbnail


Authors

Jos� A. Souto

William Lewis

Robert A. Stockman



Abstract

The thermolysis of S-aryl sulfinimines is shown to generate 1,2-disulfoxides and disulfides via initial Cope elimination, dimerisation of the produced sulfenic acid to a thiosulfinate, and subsequent disproportionation of the thiosulfinate.

Citation

Souto, J. A., Lewis, W., & Stockman, R. A. (2014). Isolation of stable non cyclic 1,2-disulfoxides: revisiting the thermolysis of S-aryl sulfinimines. Chemical Communications, 50(84), https://doi.org/10.1039/c4cc05751a

Journal Article Type Article
Acceptance Date Sep 1, 2014
Publication Date Sep 1, 2014
Deposit Date Sep 25, 2017
Publicly Available Date Sep 25, 2017
Journal Chemical Communications
Print ISSN 1359-7345
Electronic ISSN 1364-548X
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 50
Issue 84
DOI https://doi.org/10.1039/c4cc05751a
Public URL https://nottingham-repository.worktribe.com/output/733415
Publisher URL http://pubs.rsc.org/en/Content/ArticleLanding/2014/CC/C4CC05751A#!divAbstract

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