Isolation of stable non cyclic 1,2-disulfoxides: revisiting the thermolysis of S-aryl sulfinimines

Souto, Jos� A.; Lewis, William; Stockman, Robert A.

Abstract

The thermolysis of S-aryl sulfinimines is shown to generate 1,2-disulfoxides and disulfides via initial Cope elimination, dimerisation of the produced sulfenic acid to a thiosulfinate, and subsequent disproportionation of the thiosulfinate.

Citation

Souto, J. A., Lewis, W., & Stockman, R. A. (2014). Isolation of stable non cyclic 1,2-disulfoxides: revisiting the thermolysis of S-aryl sulfinimines. Chemical Communications, 50(84), https://doi.org/10.1039/c4cc05751a

• Journal Article Type: Article
• Acceptance Date: Sep 1, 2014
• Publication Date: Sep 1, 2014
• Deposit Date: Sep 25, 2017
• Publicly Available Date: Sep 25, 2017
• Journal: Chemical Communications
• Print ISSN: 1359-7345
• Electronic ISSN: 1364-548X
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 50
• Issue: 84
• DOI: https://doi.org/10.1039/c4cc05751a
• Public URL: https://nottingham-repository.worktribe.com/output/733415
• Publisher URL: http://pubs.rsc.org/en/Content/ArticleLanding/2014/CC/C4CC05751A#!divAbstract
• Contract Date: Sep 25, 2017