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A catalytic and tert-butoxide ion-mediated amidation of aldehydes with para-nitro azides

Carbone, Giorgio; Burnley, James; Moses, John E.

Authors

Giorgio Carbone

James Burnley

John E. Moses john.moses@ Nottingham.ac.uk

Abstract

We report here a new catalytic reaction in which, p-nitro azides are acylated by aldehydes to produce amides and molecular nitrogen in a single step. The transformation is believed to proceed via an electron transfer process mediated by the tert-butoxide ion, and catalysed by a thiazolium salt derived species.

Journal Article Type Article
Publication Date Feb 12, 2013
Journal Chemical Communications
Print ISSN 1359-7345
Electronic ISSN 1364-548X
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 49
Issue 27
Institution Citation Carbone, G., Burnley, J., & Moses, J. E. (2013). A catalytic and tert-butoxide ion-mediated amidation of aldehydes with para-nitro azides. Chemical Communications, 49(27), doi:10.1039/c3cc40452h
DOI https://doi.org/10.1039/c3cc40452h
Publisher URL http://pubs.rsc.org/en/Content/ArticleLanding/2013/CC/c3cc40452h
Copyright Statement Copyright information regarding this work can be found at the following address: http://eprints.nottingh.../end_user_agreement.pdf

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Copyright Statement
Copyright information regarding this work can be found at the following address: http://eprints.nottingham.ac.uk/end_user_agreement.pdf




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