Structure and thermal stability of phosphorus-iodonium ylids

Greener, Andrew; Argent, Stephen P; Clarke, Coby J; O’Duill, Miriam L

Abstract

Hypervalent iodine(III) reagents have become indispensable tools in organic synthesis, but gaps remain in the functionalities they
can transfer. In this study, a fundamental understanding of the thermal stability of phosphorus-iodonium ylids is obtained through
X-ray diffraction, differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). Insights into the structural
factors affecting thermal stability and potential decomposition pathways will enable the future design and development of new
reagents.

Citation

Greener, A., Argent, S. P., Clarke, C. J., & O’Duill, M. L. (2024). Structure and thermal stability of phosphorus-iodonium ylids. Beilstein Journal of Organic Chemistry, 20, 2931-2939. https://doi.org/10.3762/bjoc.20.245

• Journal Article Type: Article
• Acceptance Date: Oct 2, 2024
• Online Publication Date: Nov 14, 2024
• Publication Date: Nov 14, 2024
• Deposit Date: Dec 16, 2024
• Publicly Available Date: Dec 19, 2024
• Journal: Beilstein Journal of Organic Chemistry
• Print ISSN: 1860-5397
• Electronic ISSN: 1860-5397
• Publisher: Beilstein-Institut
• Peer Reviewed: Peer Reviewed
• Volume: 20
• Pages: 2931-2939
• DOI: https://doi.org/10.3762/bjoc.20.245
• Public URL: https://nottingham-repository.worktribe.com/output/41934059
• Publisher URL: https://www.beilstein-journals.org/bjoc/articles/20/245