Andrew Greener
Structure and thermal stability of phosphorus-iodonium ylids
Greener, Andrew; P. Argent, Stephen; Clarke, Coby; L. O'Duill, Miriam
Authors
STEPHEN ARGENT stephen.argent@nottingham.ac.uk
Senior Research Fellow
COBY CLARKE Coby.Clarke@nottingham.ac.uk
Research Fellow
MIRIAM O'DUILL MIRIAM.ODUILL@NOTTINGHAM.AC.UK
Assistant Professor in Chemistry
Abstract
Hypervalent iodine(III) reagents have become indispensable tools in organic synthesis, but gaps remain in the functionalities they can transfer. In this study, a fundamental understanding of the thermal stability of phosphorus-iodonium ylids is obtained through X-ray diffraction, differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). Insights into the structural factors affecting thermal stability and potential decomposition pathways will enable the future design and development of new reagents.
Citation
Greener, A., P. Argent, S., Clarke, C., & L. O'Duill, M. Structure and thermal stability of phosphorus-iodonium ylids
Working Paper Type | Preprint |
---|---|
Deposit Date | Sep 3, 2024 |
Publicly Available Date | Sep 6, 2024 |
DOI | https://doi.org/10.26434/chemrxiv-2024-4xgd6 |
Public URL | https://nottingham-repository.worktribe.com/output/38913450 |
Publisher URL | https://chemrxiv.org/engage/chemrxiv/article-details/66d00fd4a4e53c4876f7d17b |
Files
Greener_P-ylid mansucript_ChemRxiv
(777 Kb)
PDF
Publisher Licence URL
https://creativecommons.org/licenses/by-nc/4.0/
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