Glass formation via structural fragmentation of a 2D coordination network

Umeyama, D.; Funnell, N. P.; Cliffe, Matthew J.; Hill, J. A.; Goodwin, A. L.; Hijikata, Y.; Itakura, T.; Okubo, T.; Horike, S.; Kitagawa, S.

Abstract

The structure of a glass obtained by the melt quenching of a two-dimensional (2D) coordination network was examined. X-ray analyses disclosed a 2D-to-0D structural transformation before and after glass formation. The mechanism is unique to coordination compounds, as it is characterized by labile and flexible coordination bonds.

Citation

Umeyama, D., Funnell, N. P., Cliffe, M. J., Hill, J. A., Goodwin, A. L., Hijikata, Y., …Kitagawa, S. (2015). Glass formation via structural fragmentation of a 2D coordination network. Chemical Communications, 51(64), 12728-12731. https://doi.org/10.1039/c5cc04626b

• Journal Article Type: Article
• Acceptance Date: Jul 7, 2015
• Online Publication Date: Jul 7, 2015
• Publication Date: Jul 7, 2015
• Deposit Date: Dec 20, 2018
• Journal: Chemical Communications
• Print ISSN: 1359-7345
• Electronic ISSN: 1364-548X
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 51
• Issue: 64
• Pages: 12728-12731
• DOI: https://doi.org/10.1039/c5cc04626b
• Public URL: https://nottingham-repository.worktribe.com/output/1431529
• Publisher URL: https://pubs.rsc.org/en/Content/ArticleLanding/2015/CC/C5CC04626B#!divAbstract
• Additional Information: : This document is Similarity Check deposited; : Supplementary Information; : The Royal Society of Chemistry has an exclusive publication licence for this journal; : Single-blind; : Received 5 June 2015; Accepted 7 July 2015; Accepted Manuscript published 7 July 2015; Advance Article published 13 July 2015; Version of Record published 28 July 2015