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Glass formation via structural fragmentation of a 2D coordination network

Umeyama, D.; Funnell, N. P.; Cliffe, Matthew J.; Hill, J. A.; Goodwin, A. L.; Hijikata, Y.; Itakura, T.; Okubo, T.; Horike, S.; Kitagawa, S.

Authors

D. Umeyama

N. P. Funnell

J. A. Hill

A. L. Goodwin

Y. Hijikata

T. Itakura

T. Okubo

S. Horike

S. Kitagawa



Abstract

The structure of a glass obtained by the melt quenching of a two-dimensional (2D) coordination network was examined. X-ray analyses disclosed a 2D-to-0D structural transformation before and after glass formation. The mechanism is unique to coordination compounds, as it is characterized by labile and flexible coordination bonds.

Journal Article Type Article
Acceptance Date Jul 7, 2015
Online Publication Date Jul 7, 2015
Publication Date Jul 7, 2015
Deposit Date Dec 20, 2018
Journal Chemical Communications
Print ISSN 1359-7345
Electronic ISSN 1364-548X
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 51
Issue 64
Pages 12728-12731
DOI https://doi.org/10.1039/c5cc04626b
Public URL https://nottingham-repository.worktribe.com/output/1431529
Publisher URL https://pubs.rsc.org/en/Content/ArticleLanding/2015/CC/C5CC04626B#!divAbstract
Additional Information : This document is Similarity Check deposited; : Supplementary Information; : The Royal Society of Chemistry has an exclusive publication licence for this journal; : Single-blind; : Received 5 June 2015; Accepted 7 July 2015; Accepted Manuscript published 7 July 2015; Advance Article published 13 July 2015; Version of Record published 28 July 2015