Skip to main content

Research Repository

Advanced Search

A Crystalline 1D Dynamic Covalent Polymer

Authors

Elisabet

Marta

Alison Haymaker

Kyle Swain

Karol Struty?ski

Benjamin L. Weare

Javier Castells-Gil

Natalia M. Padial

Carlos

Akinori Saeki

Manuel Melle-Franco

Brent L. Nannenga

Aurelio Mateo-Alonso



Abstract

The synthesis of crystalline one-dimensional polymers provides a fundamental understanding about the structure-property relationship in polymeric materials and allows the preparation of materials with enhanced thermal, mechanical, and conducting properties. However, the synthesis of crystalline one-dimensional polymers remains a challenge because polymers tend to adopt amorphous or semicrystalline phases. Herein, we report the synthesis of a crystalline one-dimensional polymer in solution by dynamic covalent chemistry. The structure of the polymer has been unambiguously confirmed by microcrystal electron diffraction that together with charge transport studies and theoretical calculations show how the ?-stacked chains of the polymer generate optimal channels for charge transport.

Citation

De Bolòs, E., Martínez-Abadía, M., Hernández-Culebras, F., Haymaker, A., Swain, K., StrutyƄski, K., …Mateo-Alonso, A. (2022). A Crystalline 1D Dynamic Covalent Polymer. Journal of the American Chemical Society, 144(34), 15443-15450. https://doi.org/10.1021/jacs.2c06446

Journal Article Type Article
Acceptance Date Aug 5, 2022
Online Publication Date Aug 22, 2022
Publication Date Aug 31, 2022
Deposit Date Sep 10, 2022
Publicly Available Date Sep 13, 2022
Journal Journal of the American Chemical Society
Print ISSN 0002-7863
Electronic ISSN 1520-5126
Publisher American Chemical Society
Peer Reviewed Peer Reviewed
Volume 144
Issue 34
Pages 15443-15450
DOI https://doi.org/10.1021/jacs.2c06446
Keywords Colloid and Surface Chemistry; Biochemistry; General Chemistry; Catalysis
Public URL https://nottingham-repository.worktribe.com/output/10367523
Publisher URL https://pubs.acs.org/doi/10.1021/jacs.2c06446

Files





You might also like



Downloadable Citations