@article { , title = {A Crystalline 1D Dynamic Covalent Polymer}, abstract = {The synthesis of crystalline one-dimensional polymers provides a fundamental understanding about the structure-property relationship in polymeric materials and allows the preparation of materials with enhanced thermal, mechanical, and conducting properties. However, the synthesis of crystalline one-dimensional polymers remains a challenge because polymers tend to adopt amorphous or semicrystalline phases. Herein, we report the synthesis of a crystalline one-dimensional polymer in solution by dynamic covalent chemistry. The structure of the polymer has been unambiguously confirmed by microcrystal electron diffraction that together with charge transport studies and theoretical calculations show how the π-stacked chains of the polymer generate optimal channels for charge transport.}, doi = {10.1021/jacs.2c06446}, eissn = {1520-5126}, issn = {0002-7863}, issue = {34}, journal = {Journal of the American Chemical Society}, pages = {15443-15450}, publicationstatus = {Published}, publisher = {American Chemical Society (ACS)}, url = {https://nottingham-repository.worktribe.com/output/10367523}, volume = {144}, keyword = {Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis}, year = {2022}, author = {De Bolòs, Elisabet and Martínez-Abadía, Marta and Hernández-Culebras, Félix and Haymaker, Alison and Swain, Kyle and Strutyński, Karol and Weare, Benjamin L. and Castells-Gil, Javier and Padial, Natalia M. and Martí-Gastaldo, Carlos and Khlobystov, Andrei N. and Saeki, Akinori and Melle-Franco, Manuel and Nannenga, Brent L. and Mateo-Alonso, Aurelio} }