Outputs (461)

Time-dependent surface reactivity of Cd sorbed on calcite, hydroxylapatite and humic acid (2005)
Journal Article

Changes in the lability and local environment of Cd sorbed onto calcite, hydroxylapatite and humic acid have been investigated as a function of time (30 min-9 months) using a combination of X-ray adsorption spectroscopy (XAS) and isotopic dilution te... Read More about Time-dependent surface reactivity of Cd sorbed on calcite, hydroxylapatite and humic acid.

Uranyl-citrate speciation in acidic aqueous solutions - An XAS study between 25 and 200 °C (2004)
Journal Article

Speciation of uranium(VI) in citrate (2-hydroxypropane-1,2, 3-tricarboxylic acid) solutions between 25 and 200 °C, at pH values between 0.8 and 3.7 and at citrate/U ratios between 0.5 and 50 has been investigated using U LIII-edge X-ray absorption sp... Read More about Uranyl-citrate speciation in acidic aqueous solutions - An XAS study between 25 and 200 °C.

Uranyl acetate speciation in aqueous solutions-An XAS study between 25°C and 250°C (2004)
Journal Article

Speciation of uranium (VI) in acetate solutions between 25 and 250°C, at pH values between 1.8 and 3.8 and acetate/uranium (Ac/U) ratios of 0.5 to 100 has been investigated using uranium LIII-edge X-ray absorption spectroscopy. With increasing pH the... Read More about Uranyl acetate speciation in aqueous solutions-An XAS study between 25°C and 250°C.

Uranium biosorption by the lichen trapelia involuta at a uranium mine (2004)
Journal Article

Metal localisation was investigated in the lichenised ascomycete Trapelia involuta growing on a range of uraniferous minerals including metazeunerite [Cu(UO2)2(AsO42·8H2O], metatorbernite [Cu(UO22(PO4)2·8H2O], autunite [Ca(UO2)2(PO42·10H2O] and urani... Read More about Uranium biosorption by the lichen trapelia involuta at a uranium mine.

Predicting arsenic solubility in contaminated soils using isotopic dilution techniques (2002)
Journal Article

An isotopic dilution assay was developed to measure radiolabile As concentration in a diverse range of soils (pH 3.30-7.62; % C = 1.00-6.55). Soils amended with 50 mg of As kg-1 (as Na2HAsO4·7H2O) were incubated for over 800 d in an aerated "microcos... Read More about Predicting arsenic solubility in contaminated soils using isotopic dilution techniques.

A study of uranium speciation in acetate solutions at temperatures from 25 to 250°C (2001)
Journal Article

We report U L3-edge XAS analysis results from a study of the speciation of U(VI) in acetate solutions between 25 and 250°C, at pH's between 1.82 and 2.57 and [acetate]:[U] ratios of 0.5 to 50. At 25°C in excess acetate there are at least two acetate... Read More about A study of uranium speciation in acetate solutions at temperatures from 25 to 250°C.

Hydrothermal sediments associated with a relict back-arc spreading center in the Shikoku Basin, recovered from the Nankai accretionary prism, Japan (1999)
Journal Article

The hemipelagic mudrocks of the Nankai accretionary prism, Japan, contain hydrothermal deposits associated with a relict spreading center in the Shikoku Basin. Initial work on core samples from Ocean Drilling Program site 808 found several samples wi... Read More about Hydrothermal sediments associated with a relict back-arc spreading center in the Shikoku Basin, recovered from the Nankai accretionary prism, Japan.

Bioaccumulation of metals by lichens: Uptake of aqueous uranium by Peltigera membranacea as a function of time and pH (1998)
Journal Article

Uranium sorption experiments were carried out at ∼25 °C using natural samples of the lichen Peltigera membranacea. Thalli were incubated in solutions containing 100 ppm U for up to 24 h at pH values from 2 to 10. Equilibrium sorption was not observed... Read More about Bioaccumulation of metals by lichens: Uptake of aqueous uranium by Peltigera membranacea as a function of time and pH.

Role for lichen melanins in uranium remediation (1998)
Journal Article

Lichens are successful colonizers in extreme terrestrial habitats world-wide, including metalliferous environments1. Their ability to accumulate metals has led to their use in monitoring radionuclide fall-out from Chernobyl and uranium uptake from du... Read More about Role for lichen melanins in uranium remediation.

Uranium and thorium solubilities in subduction zone fluids (1994)
Journal Article

Uranium is enriched in depleted island arc magmas more than would be anticipated, due to the overall enrichment in large ion lithophile elements. To attempt to understand this enrichment calculations were performed to establish concentrations of uran... Read More about Uranium and thorium solubilities in subduction zone fluids.