Outputs (151)

Rhodium-catalyzed oxidative C–H allylation of benzamides with 1,3-dienes by allyl-to-allyl 1,4-Rh(III) migration (2016)
Journal Article

The Rh(III)-catalyzed oxidative C–H allylation of N-acetylbenzamides with 1,3-dienes is described. The presence of allylic hydrogens cis- to the less substituted alkene of the 1,3-diene is important for the success of these reactions. With the assist... Read More about Rhodium-catalyzed oxidative C–H allylation of benzamides with 1,3-dienes by allyl-to-allyl 1,4-Rh(III) migration.

Study of the Stability of 1-Alkyl-3-methylimidazolium Hexafluoroantimonate(V) Based Ionic Liquids Using X-ray Photoelectron Spectroscopy (2016)
Journal Article

A series of highly pure 1-alkyl-3-methylimidazolium hexafluoroantimonate (V) ionic liquids was firstly investigated by XPS. Reliable binding energy values for all elements within the samples were obtained by applying a C 1s fitting model previously e... Read More about Study of the Stability of 1-Alkyl-3-methylimidazolium Hexafluoroantimonate(V) Based Ionic Liquids Using X-ray Photoelectron Spectroscopy.

Catalytically active membrane-like devices: ionic liquid-hybrid organosilicas decorated with palladium nanoparticles (2016)
Journal Article

Ionic liquid (IL)-hybrid organosilicas based on 1-n-butyl-3-(3-trimethoxysilylpropyl)-imidazolium cations associated with hydrophilic and hydrophobic anions decorated with well dispersed and similar sized (1.8–2.1 nm) Pd nanoparticles (Pd-NPs) are am... Read More about Catalytically active membrane-like devices: ionic liquid-hybrid organosilicas decorated with palladium nanoparticles.

Remodeling and control of homologous recombination by DNA helicases and translocases that target recombinases and synapsis (2016)
Journal Article

Recombinase enzymes catalyse invasion of single-stranded DNA (ssDNA) into homologous duplex DNA forming "Displacement loops" (D-loops), a process called synapsis. This triggers homologous recombination (HR), which can follow several possible paths to... Read More about Remodeling and control of homologous recombination by DNA helicases and translocases that target recombinases and synapsis.

Probing polyoxometalate-protein interactions using molecular dynamics simulations (2016)
Journal Article

The molecular interactions between the Ce(IV)-substituted Keggin anion [PW11O39Ce(OH2)4]3- (CeK) and hen egg white lysozyme (HEWL), was investigated by molecular dynamics (MD) simulations. We compared the analysis of CeK with the Ce(IV)-substituted... Read More about Probing polyoxometalate-protein interactions using molecular dynamics simulations.

Selective Adsorption of Sulfur Dioxide in a Robust Metal-Organic Framework Material (2016)
Journal Article

Selective adsorption of SO2 is realized in a porous metal–organic framework material, and in-depth structural and spectroscopic investigations using X-rays, infrared, and neutrons define the underlying interactions that cause SO2 to bind more strongl... Read More about Selective Adsorption of Sulfur Dioxide in a Robust Metal-Organic Framework Material.

Coordination Chemistry of 2,2′-Bipyridyl- and 2,2′:6′,2″-Terpyridyl-Substituted BEDT-TTFs: Formation of a Supramolecular Capsule Motif by the Iron(II) Tris Complex of 2,2′-Bipyridine-4-thiomethyl-BEDT-TTF (2016)
Journal Article

Molecules of tris(2,2’-bipyridine-4-thiomethyl-BEDT-TTF)iron(II) (BEDT-TTF = bis(ethylenedithio)tetrathiafulvalene) assemble in pairs to form a novel supramolecular capsular structure in the solid state. Three BEDT-TTF residues from one complex lie i... Read More about Coordination Chemistry of 2,2′-Bipyridyl- and 2,2′:6′,2″-Terpyridyl-Substituted BEDT-TTFs: Formation of a Supramolecular Capsule Motif by the Iron(II) Tris Complex of 2,2′-Bipyridine-4-thiomethyl-BEDT-TTF.

Bridging the performance gap between electric double-layer capacitors and batteries with high-energy/high-power carbon nanotube-based electrodes (2016)
Journal Article

Electric double-layer capacitors (EDLCs) store electrical energy at the interface between charged electrodes and electrolytes and are higher-power devices than batteries. However, the amount of energy stored in EDLCs cannot compete with that in batte... Read More about Bridging the performance gap between electric double-layer capacitors and batteries with high-energy/high-power carbon nanotube-based electrodes.

Synthesis, characterization and evaluation of in vitro toxicity in hepatocytes of linear polyesters with varied aromatic and aliphatic co-monomers (2016)
Journal Article

Polyesters are extensively used in drug delivery because of their controllable biodegradation properties and perceived favorable cytocompatibility. However, new ester-based materials are continually being sought which can be produced from readily acc... Read More about Synthesis, characterization and evaluation of in vitro toxicity in hepatocytes of linear polyesters with varied aromatic and aliphatic co-monomers.

High yield and high packing density porous carbon for unprecedented CO2 capture from the first attempt at activation of air-carbonized biomass (2016)
Journal Article

The first attempt at activation of air-carbonized carbon reveals unusual resistance to activation and unprecedentedly high yields (32–80 wt%) of high packing density (0.7–1.14 g cm−3) microporous carbon dominated by 5.5–7 Å pores, which are just righ... Read More about High yield and high packing density porous carbon for unprecedented CO2 capture from the first attempt at activation of air-carbonized biomass.