Outputs (155)
Bracing copper for the catalytic oxidation of C–H bonds (2018)
Journal Article
Influence of hydrogen-bonding interactions on nuclearity and structure of palladium tiara-like complexes (2018)
Journal Article
The role of intramolecular hydrogen-bonding interactions upon the nuclearity of palladium tiara-like complexes is reported herein. The synthesis of three palladium tiaras is described with three related thiolate ligands that vary in their hydrogen-bo... Read More about Influence of hydrogen-bonding interactions on nuclearity and structure of palladium tiara-like complexes.
Syntheses of 7-substituted anthra[2,3-b]thiophene derivatives and naphtho[2,3-b:6,7-b’]dithiophene (2018)
Journal Article
7-R-anthra[2,3-b]thiophene derivatives (1, R = H, Me, i-Pr, MeO) are prepared in three steps (in average overall yield >50%) starting from (E)-4-RC6H4CH2(HOCH2)C=CI(CH2OH). The latter are commercial or readily prepared from 2-butyne-1,4-diol and ArC... Read More about Syntheses of 7-substituted anthra[2,3-b]thiophene derivatives and naphtho[2,3-b:6,7-b’]dithiophene.
Substrate-induced shifts and screening in the fluorescence spectra of supramolecular adsorbed organic monolayers (2018)
Journal Article
We have investigated the influence of the substrate on the fluorescence of adsorbed organic molecules. Monolayer films of perylene-3,4,9,10-tetracarboxylic-3,4,9,10-diimide (PTCDI), a supramolecular network formed from PTCDI and melamine, and perylen... Read More about Substrate-induced shifts and screening in the fluorescence spectra of supramolecular adsorbed organic monolayers.
Supramolecular interaction of non-racemic benzimidazolium based ion pairs with chiral substrates (2018)
Journal Article
A series of novel benzimidazolium-based non-racemic ionic liquids (ILs) was synthesized from low–cost chiral terpenoid alcohols and fully characterized by the use of a wide variety of techniques, such as DSC, ESI-MS, ATR FT-IR, polarimetry as well as... Read More about Supramolecular interaction of non-racemic benzimidazolium based ion pairs with chiral substrates.
Expanding the Color Space in the Two-Color Heterogeneous Photocatalysis of Ullmann C–C Coupling Reactions (2018)
Journal Article
The Ullmann reaction can be heterogeneously photocatalyzed by UV excitation of Pd@TiO2. While a similar dose of visible light does not initiate the reaction, combination with UV light enhances activity and selectivity toward cross-combination product... Read More about Expanding the Color Space in the Two-Color Heterogeneous Photocatalysis of Ullmann C–C Coupling Reactions.
Kohn–Sham energy decomposition for molecules in a magnetic field (2018)
Journal Article
We study the total molecular electronic energy and its Kohn–Sham components within the framework of magnetic-field density-functional theory (BDFT), an alternative to current-dependent density-functional theory (CDFT) for molecules in the presence of... Read More about Kohn–Sham energy decomposition for molecules in a magnetic field.
Remote Nucleophilic Allylation by Allylrhodium Chain Walking (2018)
Journal Article
Metal migration through a carbon chain is a versatile method for achieving remote functionalization. However, almost all known examples involve the overall net migration of alkylmetal species. Here, we report that allylrhodium species obtained from h... Read More about Remote Nucleophilic Allylation by Allylrhodium Chain Walking.
Capturing waste heat energy with charge-transfer organic thermoelectrics (2018)
Journal Article
Electrically conducting organic salts, known for over 60 years, have recently demonstrated new abilities to convert waste heat directly into electrical power via the thermoelectric effect. Multiple opportunities are emerging for new structure-propert... Read More about Capturing waste heat energy with charge-transfer organic thermoelectrics.