All Outputs (55)

Photophysics of 7-mercapto-4-methylcoumarin and derivatives: complementary fluorescence behaviour to 7-hydroxycoumarins (2017)
Journal Article
Lanterna, A. E., González-Béjar, M., Frenette, M., & Scaiano, J. C. (2017). Photophysics of 7-mercapto-4-methylcoumarin and derivatives: complementary fluorescence behaviour to 7-hydroxycoumarins. Photochemical & Photobiological Sciences Photochemical and Photobiological Sciences, 16(8), 1284-1289. https://doi.org/10.1039/c7pp00121e

The photophysical behaviour of 7-mercapto-4-methylcoumarin (C-SH) and derivatives has been studied in different solvents. In contrast to 7-hydroxy-4-methylcoumarin, C-SH shows poor emission, but high fluorescence when the thiol is alkylated. The orig... Read More about Photophysics of 7-mercapto-4-methylcoumarin and derivatives: complementary fluorescence behaviour to 7-hydroxycoumarins.

Is Single-Molecule Fluorescence Spectroscopy Ready To Join the Organic Chemistry Toolkit? A Test Case Involving Click Chemistry (2017)
Journal Article
Scaiano, J. C., & Lanterna, A. E. (2017). Is Single-Molecule Fluorescence Spectroscopy Ready To Join the Organic Chemistry Toolkit? A Test Case Involving Click Chemistry. Journal of Organic Chemistry, 82(10), 5011-5019. https://doi.org/10.1021/acs.joc.6b03010

Single molecule spectroscopy (SMS) has matured to a point where it can be used as a convenient tool to guide organic synthesis and drug discovery, particularly applicable to catalytic systems where questions related to homogeneous vs heterogeneous pa... Read More about Is Single-Molecule Fluorescence Spectroscopy Ready To Join the Organic Chemistry Toolkit? A Test Case Involving Click Chemistry.

Tunable Photocatalytic Activity of Palladium-Decorated TiO2: Non-Hydrogen-Mediated Hydrogenation or Isomerization of Benzyl-Substituted Alkenes (2016)
Journal Article
Elhage, A., Lanterna, A. E., & Scaiano, J. C. (2017). Tunable Photocatalytic Activity of Palladium-Decorated TiO2: Non-Hydrogen-Mediated Hydrogenation or Isomerization of Benzyl-Substituted Alkenes. ACS Catalysis, 7(1), 250-255. https://doi.org/10.1021/acscatal.6b02832

Palladium-decorated TiO2 is a moisture- and air-tolerant versatile catalyst. Its photocatalytic activity can be tuned in favor of hydrogenation or isomerization of benzyl-substituted alkenes simply by changing the irradiation wavelength. Benzyl-subst... Read More about Tunable Photocatalytic Activity of Palladium-Decorated TiO2: Non-Hydrogen-Mediated Hydrogenation or Isomerization of Benzyl-Substituted Alkenes.

From the molecule to the mole: improving heterogeneous copper catalyzed click chemistry using single molecule spectroscopy (2016)
Journal Article
Wang, B., Durantini, J., Decan, M. R., Nie, J., Lanterna, A. E., & Scaiano, J. C. (2017). From the molecule to the mole: improving heterogeneous copper catalyzed click chemistry using single molecule spectroscopy. Chemical Communications, 53(2), 328-331. https://doi.org/10.1039/c6cc08905d

Single molecule spectroscopy (SMS) inspired the optimization of a heterogeneous ‘click’ catalyst leading to enhanced yields of the Cu-catalyzed reaction of azides with terminal alkynes. Changes in SMS data after optimization confirm the improvements... Read More about From the molecule to the mole: improving heterogeneous copper catalyzed click chemistry using single molecule spectroscopy.

Heterogeneous Photocatalytic Click Chemistry (2016)
Journal Article
Wang, B., Durantini, J., Nie, J., Lanterna, A. E., & Scaiano, J. C. (2016). Heterogeneous Photocatalytic Click Chemistry. Journal of the American Chemical Society, 138(40), 13127-13130. https://doi.org/10.1021/jacs.6b06922

Copper-doped semiconductors are designed to photoassist the alkyne-azide cycloaddition catalysis by Cu(I). Upon irradiation, injection of electrons from the semiconductor into copper oxide nanostructures produces the catalytic Cu(I) species. The new... Read More about Heterogeneous Photocatalytic Click Chemistry.

Improving the Sunscreen Properties of TiO2 through an Understanding of Its Catalytic Properties (2016)
Journal Article
Morsella, M., d’Alessandro, N., Lanterna, A. E., & Scaiano, J. C. (2016). Improving the Sunscreen Properties of TiO2 through an Understanding of Its Catalytic Properties. ACS Omega, 1(3), 464-469. https://doi.org/10.1021/acsomega.6b00177

The use of particulate titanium dioxide (TiO2) as an active sunscreen ingredient has raised concerns about potential risks from TiO2-mediated free radical formation. To date, remediation attempts have concentrated on reducing the yield of free radica... Read More about Improving the Sunscreen Properties of TiO2 through an Understanding of Its Catalytic Properties.

Catalyst Decomposition during Olefin Metathesis Yields Isomerization-Active Ruthenium Nanoparticles (2016)
Journal Article
Higman, C. S., Lanterna, A. E., Marin, M. L., Scaiano, J. C., & Fogg, D. E. (2016). Catalyst Decomposition during Olefin Metathesis Yields Isomerization-Active Ruthenium Nanoparticles. ChemCatChem, 8(15), 2446-2449. https://doi.org/10.1002/cctc.201600738

The second‐generation Grubbs catalyst, RuCl2(H2IMes)(PCy3) (=CHPh) [GII ; H2IMes=1,3‐bis(2,4,6‐trimethylphenyl)‐4,5‐dihydroimidazol‐2‐ylidene, Cy=cyclohexyl], is shown to decompose during olefin metathesis to generate Ru nanoparticles (RuNPs). These... Read More about Catalyst Decomposition during Olefin Metathesis Yields Isomerization-Active Ruthenium Nanoparticles.

Two-Photon Excitation of a Plasmonic Nanoswitch Monitored by Single-Molecule Fluorescence Microscopy (2016)
Journal Article
Impellizzeri, S., Simoncelli, S., Hodgson, G. K., Lanterna, A. E., McTiernan, C. D., Raymo, F. M., …Scaiano, J. C. (2016). Two-Photon Excitation of a Plasmonic Nanoswitch Monitored by Single-Molecule Fluorescence Microscopy. Chemistry - A European Journal, 22(21), 7281-7287. https://doi.org/10.1002/chem.201600218

Visible‐light excitation of the surface plasmon band of silver nanoplates can effectively localize and concentrate the incident electromagnetic field enhancing the photochemical performance of organic molecules. Herein, the first single‐molecule stud... Read More about Two-Photon Excitation of a Plasmonic Nanoswitch Monitored by Single-Molecule Fluorescence Microscopy.

A Mechanistic Study of Halogen Addition and Photoelimination from π-Conjugated Tellurophenes (2016)
Journal Article
Carrera, E. I., Lanterna, A. E., Lough, A. J., Scaiano, J. C., & Seferos, D. S. (2016). A Mechanistic Study of Halogen Addition and Photoelimination from π-Conjugated Tellurophenes. Journal of the American Chemical Society, 138(8), 2678-2689. https://doi.org/10.1021/jacs.5b11649

The ability to drive reactivity using visible light is of importance for many disciplines of chemistry and has significant implications for sustainable chemistry. Identifying photochemically active compounds and understanding photochemical mechanisms... Read More about A Mechanistic Study of Halogen Addition and Photoelimination from π-Conjugated Tellurophenes.

Synthesis of gold nanoparticles using electron-donating dithiafulvene units (2015)
Journal Article
Lanterna, A. E., Coronado, E. A., & Granados, A. M. (2020). Synthesis of gold nanoparticles using electron-donating dithiafulvene units. Tetrahedron Letters, 56(34), 4871-4876. https://doi.org/10.1016/j.tetlet.2015.06.064

Dithiafulvene (DTF) derivative compounds were used as reducing agents to synthesize capped gold nanoparticles (AuNPs). DTF derivatives had shown good capability to reduce Au(III) to Au(0) without further addition of common reducing agents, and at the... Read More about Synthesis of gold nanoparticles using electron-donating dithiafulvene units.

Heterogeneous photocatalytic C–C coupling: mechanism of plasmon-mediated reductive dimerization of benzyl bromides by supported gold nanoparticles (2015)
Journal Article
Lanterna, A. E., Elhage, A., & Scaiano, J. C. (2015). Heterogeneous photocatalytic C–C coupling: mechanism of plasmon-mediated reductive dimerization of benzyl bromides by supported gold nanoparticles. Catalysis Science and Technology, 5(9), 4336-4340. https://doi.org/10.1039/c5cy00655d

The use of gold nanoparticles supported on TiO2 (Au@TiO2) as photocatalysts was extended to include photoinduced reductive C–C coupling. Surface plasmon excitation of supported AuNPs in the presence of an amine leads to the C–C coupling of a variety... Read More about Heterogeneous photocatalytic C–C coupling: mechanism of plasmon-mediated reductive dimerization of benzyl bromides by supported gold nanoparticles.

Enhanced catalytic electrochemical reduction of dissolved oxygen with ultraclean cucurbituril[7]-capped gold nanoparticles (2014)
Journal Article
Lanterna, A., Pino, E., Doménech-Carbó, A., González-Béjar, M., & Pérez-Prieto, J. (2014). Enhanced catalytic electrochemical reduction of dissolved oxygen with ultraclean cucurbituril[7]-capped gold nanoparticles. Nanoscale, 6(16), 9550-9553. https://doi.org/10.1039/c4nr01967a

Gold nanoparticles capped with cucurbituril[7] have been prepared in the absence of metallic cations and organic ligands. Remarkably, these nanohybrids encapsulate dissolved oxygen and are highly active in electrochemical reduction. The effect of the... Read More about Enhanced catalytic electrochemical reduction of dissolved oxygen with ultraclean cucurbituril[7]-capped gold nanoparticles.

Distinctive Interactions of Oleic Acid Covered Magnetic Nanoparticles with Saturated and Unsaturated Phospholipids in Langmuir Monolayers (2014)
Journal Article
Matshaya, T. J., Lanterna, A. E., Granados, A. M., Krause, R. W. M., Maggio, B., & Vico, R. V. (2014). Distinctive Interactions of Oleic Acid Covered Magnetic Nanoparticles with Saturated and Unsaturated Phospholipids in Langmuir Monolayers. Langmuir, 30(20), 5888-5896. https://doi.org/10.1021/la500903m

The growing number of innovations in nanomedicine and nanobiotechnology are posing new challenges in understanding the full spectrum of interactions between nanomateriales and biomolecules at nano-biointerfaces. Although considerable achievements hav... Read More about Distinctive Interactions of Oleic Acid Covered Magnetic Nanoparticles with Saturated and Unsaturated Phospholipids in Langmuir Monolayers.

Thiosaccharine disulfide: Synthesis, crystal structure, spectroscopic characterization and theoretical study (2012)
Journal Article
Ferullo, R. M., Granados, A., Lanterna, A., Güida, J. A., Piro, O. E., Castellano, E. E., & Dennehy, M. (2013). Thiosaccharine disulfide: Synthesis, crystal structure, spectroscopic characterization and theoretical study. Journal of Molecular Structure, 1032, 48-55. https://doi.org/10.1016/j.molstruc.2012.07.043

The title compound, (thiosaccharine disulfide), bis[1,1′dioxide-2,3-dihidro-1,2-benzoisothiazol]disulfide, (tsac)2 has been synthesized and fully characterized by UV–Visible, IR, Raman, 1H and 13C NMR spectroscopy elemental analysis and structural X-... Read More about Thiosaccharine disulfide: Synthesis, crystal structure, spectroscopic characterization and theoretical study.

When Nanoparticle Size and Molecular Geometry Matter: Analyzing the Degree of Surface Functionalization of Gold Nanoparticles with Sulfur Heterocyclic Compounds (2012)
Journal Article
Lanterna, A. E., Coronado, E. A., & Granados, A. M. (2012). When Nanoparticle Size and Molecular Geometry Matter: Analyzing the Degree of Surface Functionalization of Gold Nanoparticles with Sulfur Heterocyclic Compounds. Journal of Physical Chemistry C, 116(11), 6520-6529. https://doi.org/10.1021/jp209816g

The degree of surface functionalization of colloidal dispersions of Au nanoparticles (AuNPs) by sulfur heterocyclic compounds is determined using localized surface plasmon resonance spectroscopy (LSPRS), morphological characterization, and electrodyn... Read More about When Nanoparticle Size and Molecular Geometry Matter: Analyzing the Degree of Surface Functionalization of Gold Nanoparticles with Sulfur Heterocyclic Compounds.