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The use of electron probe microanalysis and laser ablation-inductively coupled plasma-mass spectrometry for the investigation of 8th–14th century plant ash glasses from the Middle East

Henderson, Julian; Chenery, Simon; Faber, Edward; Kroeger, Jens

Authors

Simon Chenery srch@bgs.ac.uk

Edward Faber

Jens Kroeger jens.sasan.kroeger@gmx.net



Abstract

This is the first broad survey using major, minor and trace element analysis of 8th-15th AD plant ash glass from the Middle East across a 2000 mile area stretching from Egypt to northern Iran. This was part of the ancient Silk Road that extended from the Middle East, through central Asia to China. Up to now, some compositional distinctions have been identified for such glasses mainly using major and minor element oxides and radiogenic isotopes. Our new trace element characterisation is for glass found in selected cosmopolitan hubs, including one where there is archaeological evidence for primary glass making. It provides not only far clearer provenance definitions for regional centres of production, in the Levant, northern Syria and in Iraq and Iran, but also for sub-regional zones of production. This fingerprinting is provided by trace elements associated with the primary glass making raw materials used: ashed halophytic plants and sands. Even more surprising is a correlation between some of the sub-regional production hubs and the types of glass vessels with diagnostic decoration apparently manufactured in or near the cosmopolitan hubs where the glass was found such as colourless cut and engraved vessels (in Iraq and Iran) and trail-decorated vessels (in the Levant). This therefore provides evidence for centres of specialisation. Our trace element characterisation provides a new way of defining the Silk Road by characterising the glass that was traded or exchanged along it. Taken together this data provides a new decentralised model for ancient glass production.

Citation

Henderson, J., Chenery, S., Faber, E., & Kroeger, J. (2016). The use of electron probe microanalysis and laser ablation-inductively coupled plasma-mass spectrometry for the investigation of 8th–14th century plant ash glasses from the Middle East. Microchemical Journal, 128, https://doi.org/10.1016/j.microc.2016.03.013

Journal Article Type Article
Acceptance Date Mar 21, 2016
Online Publication Date Apr 16, 2016
Publication Date Sep 1, 2016
Deposit Date Aug 1, 2016
Publicly Available Date Aug 1, 2016
Journal Microchemical Journal
Print ISSN 0026-265X
Electronic ISSN 0026-265X
Publisher Elsevier
Peer Reviewed Peer Reviewed
Volume 128
DOI https://doi.org/10.1016/j.microc.2016.03.013
Keywords Glass technology, Trace element analysis, Provenance
Public URL http://eprints.nottingham.ac.uk/id/eprint/35578
Publisher URL http://www.sciencedirect.com/science/article/pii/S0026265X1630011X
Copyright Statement Copyright information regarding this work can be found at the following address: http://creativecommons.org/licenses/by-nc-nd/4.0

Files

Michrochemical Journal Text NU.pdf (1.1 Mb)
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Copyright Statement
Copyright information regarding this work can be found at the following address: http://creativecommons.org/licenses/by-nc-nd/4.0





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