Dehydrogenation of dimethylamine-borane mediated by Group 1 pincer complexes

Nolla-Saltiel, Roberto; Geer, Ana M; Lewis, William; Blake, Alexander J.; Kays, Deborah L.

Abstract

Group 1 salts containing carbazolido NNN pincer ligands are precatalysts for the dehydrogenation of Me2NH·BH3. NMR monitoring and DOSY studies show a heavy dependence on the metal and solvent, allowing in some cases selective formation of dehydrogenation products consistent with hydrogen liberation.

Citation

Nolla-Saltiel, R., Geer, A. M., Lewis, W., Blake, A. J., & Kays, D. L. (2018). Dehydrogenation of dimethylamine-borane mediated by Group 1 pincer complexes. Chemical Communications, 54(15), https://doi.org/10.1039/c7cc08385h

• Journal Article Type: Article
• Acceptance Date: Jan 4, 2018
• Online Publication Date: Jan 4, 2018
• Publication Date: Feb 21, 2018
• Deposit Date: Feb 16, 2018
• Publicly Available Date: Jan 5, 2019
• Journal: Chemical Communications
• Print ISSN: 1359-7345
• Electronic ISSN: 1364-548X
• Publisher: Royal Society of Chemistry
• Peer Reviewed: Peer Reviewed
• Volume: 54
• Issue: 15
• DOI: https://doi.org/10.1039/c7cc08385h
• Public URL: https://nottingham-repository.worktribe.com/output/913208
• Publisher URL: http://pubs.rsc.org/en/content/articlelanding/2018/cc/c7cc08385h#!divAbstract
• Contract Date: Feb 16, 2018