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Dehydrogenation of dimethylamine-borane mediated by Group 1 pincer complexes

Nolla-Saltiel, Roberto; Geer, Ana M; Lewis, William; Blake, Alexander J.; Kays, Deborah L.

Authors

Roberto Nolla-Saltiel

Ana M Geer

William Lewis

Alexander J. Blake

DEBORAH KAYS deborah.kays@nottingham.ac.uk
Professor of Inorganic Chemistry



Abstract

Group 1 salts containing carbazolido NNN pincer ligands are precatalysts for the dehydrogenation of Me2NH·BH3. NMR monitoring and DOSY studies show a heavy dependence on the metal and solvent, allowing in some cases selective formation of dehydrogenation products consistent with hydrogen liberation.

Citation

Nolla-Saltiel, R., Geer, A. M., Lewis, W., Blake, A. J., & Kays, D. L. (2018). Dehydrogenation of dimethylamine-borane mediated by Group 1 pincer complexes. Chemical Communications, 54(15), https://doi.org/10.1039/c7cc08385h

Journal Article Type Article
Acceptance Date Jan 4, 2018
Online Publication Date Jan 4, 2018
Publication Date Feb 21, 2018
Deposit Date Feb 16, 2018
Publicly Available Date Jan 5, 2019
Journal Chemical Communications
Print ISSN 1359-7345
Electronic ISSN 1364-548X
Publisher Royal Society of Chemistry
Peer Reviewed Peer Reviewed
Volume 54
Issue 15
DOI https://doi.org/10.1039/c7cc08385h
Public URL http://eprints.nottingham.ac.uk/id/eprint/49825
Publisher URL http://pubs.rsc.org/en/content/articlelanding/2018/cc/c7cc08385h#!divAbstract
Copyright Statement Copyright information regarding this work can be found at the following address: http://eprints.nottingham.ac.uk/end_user_agreement.pdf

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Copyright Statement
Copyright information regarding this work can be found at the following address: http://eprints.nottingham.ac.uk/end_user_agreement.pdf





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