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Enantioselective rhodium-catalyzed coupling of arylboronic acids, 1,3-enynes, and Imines by alkenyl-to-allyl 1,4-rhodium(I) migration

Callingham, Michael; Partridge, Benjamin M.; Lewis, William; Lam, Hon Wai

Authors

Michael Callingham michael.callingham@nottingham.ac.uk

Benjamin M. Partridge benjamin.partridge@nottingham.ac.uk

William Lewis

HON LAM Hon.Lam@nottingham.ac.uk
Professor of Sustainable Chemistry



Abstract

A chiral rhodium complex catalyzes the highly enantioselective coupling of arylboronic acids, 1,3-enynes, and imines to give homoallylic sulfamates. The key step is the generation of allylrhodium(I) species by alkenyl-to-allyl 1,4-rhodium(I) migration.

Citation

Callingham, M., Partridge, B. M., Lewis, W., & Lam, H. W. (2017). Enantioselective rhodium-catalyzed coupling of arylboronic acids, 1,3-enynes, and Imines by alkenyl-to-allyl 1,4-rhodium(I) migration. Angewandte Chemie International Edition, 56(51), https://doi.org/10.1002/anie.201709334

Journal Article Type Article
Acceptance Date Oct 4, 2017
Online Publication Date Nov 24, 2017
Publication Date Dec 18, 2017
Deposit Date Oct 16, 2017
Publicly Available Date Nov 24, 2017
Journal Angewandte Chemie International Edition
Print ISSN 1433-7851
Electronic ISSN 1521-3773
Publisher Wiley
Peer Reviewed Peer Reviewed
Volume 56
Issue 51
DOI https://doi.org/10.1002/anie.201709334
Keywords arylboronic acid; 1,4-migration; imine
Public URL http://eprints.nottingham.ac.uk/id/eprint/47300
Publisher URL http://onlinelibrary.wiley.com/doi/10.1002/anie.201709334/abstract
Copyright Statement Copyright information regarding this work can be found at the following address: http://creativecommons.org/licenses/by/4.0

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Copyright Statement
Copyright information regarding this work can be found at the following address: http://creativecommons.org/licenses/by/4.0





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