Constance R. Pfeiffer
Nickel(II) metal-organic frameworks with N,N’-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide ligands: influence of secondary building unit geometry on dimensionality and framework dimensions
Pfeiffer, Constance R.; Biggins, Naomi H.; Lewis, William; Champness, Neil R.
Authors
Naomi H. Biggins
William Lewis
Neil R. Champness
Abstract
When Ni(NO3)2∙6H2O and N,N’-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (DPNDI) are reacted, a one-dimensional coordination polymer (1) is formed. However, reaction with either terephthalic acid (2) or 2,6-naphthalenedicarboxylic acid (3) affords two-dimensional, pillared metal-organic frameworks. 2 and 3 containing rectangular voids of different dimensions which are dictated by the carboxylate ligand and the arrangement of the [M(k2-O2NO)]2(μ2-O2CR)2] secondary building unit (SBU) that forms the nodes of the framework. The role of SBU geometry, intermolecular face-to-face π–π and lone pair–π interactions involving the DPNDI ligands are discussed.
Citation
Pfeiffer, C. R., Biggins, N. H., Lewis, W., & Champness, N. R. (2017). Nickel(II) metal-organic frameworks with N,N’-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide ligands: influence of secondary building unit geometry on dimensionality and framework dimensions. CrystEngComm, 19, https://doi.org/10.1039/C7CE00956A
Journal Article Type | Article |
---|---|
Acceptance Date | Aug 25, 2017 |
Publication Date | Sep 5, 2017 |
Deposit Date | Oct 4, 2017 |
Publicly Available Date | Sep 6, 2018 |
Journal | CrystEngComm |
Electronic ISSN | 1466-8033 |
Publisher | Royal Society of Chemistry |
Peer Reviewed | Peer Reviewed |
Volume | 19 |
DOI | https://doi.org/10.1039/C7CE00956A |
Keywords | Metal-organic frameworks, N,N’-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide, nickel (II) frameworks, pillared frameworks |
Public URL | https://nottingham-repository.worktribe.com/output/880932 |
Publisher URL | http://pubs.rsc.org/en/content/articlelanding/2017/ce/c7ce00956a#!divAbstract |
Contract Date | Oct 4, 2017 |
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